Mixed ligand complexes in vinyl polymerization-II: [NN-ethylenebis(salicylideneiminato)] (benzoylacetonato)cobalt(III) as an initiator
| Data(s) |
1982
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|---|---|
| Resumo |
The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN-ethylenebis(salicylideneiminato)](benzoylacetonato)cobalt(III) has been studied in bulk and in benzene at 70° and 80°. The rate of polymerization is proportional to (concentration of the chelate)Image and the monomer exponent is close to 1.5. The activation energy and the kinetic and transfer constants are evaluated. A free radical mechanism has been proposed. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/22486/1/fullpdf.pdf Thiagarajan, R and Nandi, US and Kalpagam, V (1982) Mixed ligand complexes in vinyl polymerization-II: [NN-ethylenebis(salicylideneiminato)] (benzoylacetonato)cobalt(III) as an initiator. In: European Polymer Journal, 18 (3). pp. 261-264. |
| Publicador |
Elsevier Science |
| Relação |
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TWW-48GX59W-JX&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=5c0d4837bc4bb23cbbb0b4fbbd6aa9e5 http://eprints.iisc.ernet.in/22486/ |
| Palavras-Chave | #Inorganic & Physical Chemistry |
| Tipo |
Journal Article PeerReviewed |
