Ternary vanadium sulfides


Autoria(s): Murugesan, T; Rao, CNR; Gopalakrishnan, J; Ramesh, S
Data(s)

01/08/1982

Resumo

Ternary vanadium sulfides, MxVS2 (M = Fe, Co, Ni), with Image , were prepared and studied. The Image and Image series are isostructural with V5S8 and V3S4, respectively, while compounds with Image appear to have the hexagonal Cr2S3 structure. Structures of NiV2S4 and NiV4S8 were refined from powder X-ray diffraction intensities. Magnetic and electrical properties reveal that M ions in these sulfides exist in the divalent state having localized moments, while the vanadium 3 d electrons are itinerant.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/22335/1/sdarticle.pdf

Murugesan, T and Rao, CNR and Gopalakrishnan, J and Ramesh, S (1982) Ternary vanadium sulfides. In: Journal of Solid State Chemistry, 44 (1). pp. 119-125.

Publicador

Elsevier Science

Relação

http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6WM2-4B6NV81-K8&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=0ef94f08fa55860381e95f2a9d6dda90

http://eprints.iisc.ernet.in/22335/

Palavras-Chave #Solid State & Structural Chemistry Unit
Tipo

Journal Article

PeerReviewed