Solubilities of solids in supercritical fluids using dimensionally consistent modified solvate complex models


Autoria(s): Garlapati, Chandrasekhar; Madras, Giridhar
Data(s)

01/09/2009

Resumo

New dimensionally consistent modified solvate complex models are derived to correlate solubilities of solids in supercritical fluids both in the presence and absence of entrainers (cosolvents). These models are compared against the standard solvate complex models [J.Chrastil, J. Phys. Chem. 86 (1982) 3016-3021; J.C. Gonzalez, M.R.Vieytes, A.M. Botana, J.M. Vieites, L.M. Botana, J. Chromatogr. A 910 (2001) 119-125; Y. Adachi, B.C.Y. Lu, Fluid Phase Equilb. 14 (1983) 47-156; J.M. del Valle, J.M. Aguilera, Ind. Eng. Chem. Res. 27 (1988) 1551-1553] by correlating the solubilities of 13 binary and 12 ternary systems. Though the newly derived models are not significantly better than the standard models in predicting the solubilities, they are dimensionally consistent. (C) 2009 Elsevier B.V. All rights reserved.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/22275/1/full_text_3.pdf

Garlapati, Chandrasekhar and Madras, Giridhar (2009) Solubilities of solids in supercritical fluids using dimensionally consistent modified solvate complex models. In: Fluid Phase Equilibria, 283 (1-2). pp. 97-101.

Publicador

Elsevier B.V.

Relação

http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TG2-4WCSR8K-2&_user=512776&_rdoc=1&_fmt=&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=c96f6cfd6c74d221f114e024c0fc233c

http://eprints.iisc.ernet.in/22275/

Palavras-Chave #Chemical Engineering
Tipo

Journal Article

PeerReviewed