Synthesis and physico-chemical properties of diruthenium(III, II) tetra-aryl carboxylato compounds
| Data(s) |
1988
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|---|---|
| Resumo |
Monochloro-tetra-μ-aryl-carboxylatodiruthenium(III, II) compounds Ru2Cl (O2CAr)4 (Ar = -C6H5; -C6H4-p-OCH3), are prepared and characterized. The compounds have magnetic moments that correspond to three unpaired spins per dimer. The Rusingle bondRu bond order is 2.5 and the ground electronic configuration is σ2π4δ2(δ*π*)3. The visible spectral band is observed at ca 450 nm along with a shoulder near 580 nm in DMF solution. The compounds undergo a one-electron Ru(III)Ru(II) → Ru(II)Ru(II) quasi-reversible reduction in DMF near 0.0 V vs sce. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/22022/1/pdf.pdf Das, Birinchi K and Chakravarty, R (1988) Synthesis and physico-chemical properties of diruthenium(III, II) tetra-aryl carboxylato compounds. In: Polyhedron, 7 (9). pp. 685-687. |
| Publicador |
Elsevier science |
| Relação |
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TH8-4GDJ7M0-4&_user=512776&_coverDate=12%2F31%2F1988&_rdoc=1&_fmt=high&_orig=search&_sort=d&_docanchor=&view=c&_acct=C000025298&_version=1&_urlVersion=0&_userid=512776&md5=2edf89483dfa1bcae01f5de0 http://eprints.iisc.ernet.in/22022/ |
| Palavras-Chave | #Inorganic & Physical Chemistry |
| Tipo |
Journal Article PeerReviewed |
