Stabilization of the Alleged 'Bishomoaromatic' Bicyclo[3.2.l]octa-2,6-dienyl Anion by Counterion Interactions and by Hyperconjugation
| Data(s) |
01/11/1986
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|---|---|
| Resumo |
Hyperconjugation and inductive effects, rather than homoaromaticity, are responsible for the stabilization of the title anion in the gas phase; interaction of the double bond with the Li+ gegenion in the endo geometry contributes additionally in solution. |
| Formato |
application/pdf |
| Identificador |
http://eprints.iisc.ernet.in/20776/1/C39860001583.pdf Rague Schleyer, Paul von and Kaufmann, Elmar and Kos, Alexander J and Mayr, Herbert and Chandrasekhard, Jayaraman (1986) Stabilization of the Alleged 'Bishomoaromatic' Bicyclo[3.2.l]octa-2,6-dienyl Anion by Counterion Interactions and by Hyperconjugation. In: Journal of the Chemical Society - Series Chemical Communications (21). 1583 -1585. |
| Publicador |
Royal Society Chemistry |
| Relação |
http://www.rsc.org/publishing/journals/C3/article.asp?doi=c39860001583 http://eprints.iisc.ernet.in/20776/ |
| Palavras-Chave | #Organic Chemistry |
| Tipo |
Journal Article PeerReviewed |
