Dimethyl 2,2 `-[(4-oxo-2-phenyl-4H-chromene 5,7-diyl)dioxy]diacetate: a more densely packed polymorph


Autoria(s): Nallasivam, Angannan; Nethaji, Munirathinam; Vembu, Nagarajan; Jaswant, Buckle; Sulochana, Nagarajan
Data(s)

01/02/2009

Resumo

The title molecule, C21H18O8, crystallizes in two crystal polymorphs, see also Nallasivam, Nethaji, Vembu & Jaswant [Acta Cryst. (2009), E65, o314-o315]. The molecules of both polymorphs differ by the conformation of the oxomethylacetate groups. The title molecules are rather planar compared to the molecules of the other polymorph. In the title molecule, one of the oxomethylacetate groups is disordered (occupancies of 0.6058/0.3942). The structures of both polymorphs are stabilized by C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions. Due to the planarity of the title molecules and similar intermolecular interactions, the title molecules are more densely packed than those of the other polymorph.

Formato

application/pdf

Identificador

http://eprints.iisc.ernet.in/19365/1/2.pdf

Nallasivam, Angannan and Nethaji, Munirathinam and Vembu, Nagarajan and Jaswant, Buckle and Sulochana, Nagarajan (2009) Dimethyl 2,2 `-[(4-oxo-2-phenyl-4H-chromene 5,7-diyl)dioxy]diacetate: a more densely packed polymorph. In: Acta Crystallographica Section E-Structure Reports Online, 65 (Part 2). O312-O313.

Publicador

International Union of Crystallography

Relação

http://scripts.iucr.org/cgi-bin/paper?S1600536809001020

http://eprints.iisc.ernet.in/19365/

Palavras-Chave #Inorganic & Physical Chemistry
Tipo

Journal Article

PeerReviewed