Synthesis of imines from amines in aliphatic alcohols on Pd/ZrO2 catalyst under ambient conditions


Autoria(s): Cui, Wenjing; Zhaorigetu, Bao; Jia, Meilin; Ao, Wulan; Zhu, Huai Yong
Data(s)

2014

Resumo

Synthesis of imines from amines and aliphatic alcohols (C1–C6) in the presence of base on supported palladium nanoparticles has been achieved for the first time. The catalytic system shows high activity and selectivity in open air at room temperature. As an example of the isostructural Ln3Sb3Co2O14 (Ln: La, Pr, Nd, Sm—Ho) series with an ordered pyrochlore structure, the La variant is prepared by a citrate complex method employing stoichiometric amounts of La(NO3)3, Co(NO3)2, and Sb tartrate together with citric acid with a metal/citrate molar ratio of 1:2

Identificador

http://eprints.qut.edu.au/80344/

Publicador

RSC Publications

Relação

DOI:10.1039/c3ra44625e

Cui, Wenjing, Zhaorigetu, Bao, Jia, Meilin, Ao, Wulan, & Zhu, Huai Yong (2014) Synthesis of imines from amines in aliphatic alcohols on Pd/ZrO2 catalyst under ambient conditions. RSC Advances: an international journal to further the chemical sciences, 4(6), pp. 2601-2604.

Fonte

School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty

Palavras-Chave #039900 OTHER CHEMICAL SCIENCES #Synthesis of imines #structure (solids and liquids);lanthanoids;cobalt, Co;antimony, Sb;dielectric properties, magnetic properties
Tipo

Journal Article