Molecular camouflage : making use of protecting groups to control the self-assembly of inorganic janus particles onto metal–chalcogenide nanotubes by Pearson Hardness
Data(s) |
16/12/2011
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Resumo |
Hard and soft: Binding of inorganic Pt@Fe3O4 Janus particles to WS2 nanotubes through their Pt or Fe3O4 domains is governed by the difference in Pearson hardness: the soft Pt block has a higher sulfur affinity than the harder magnetite face; thus the binding proceeds preferentially through the Pt face. This binding preference can be reversed by masking the Pt face with an organic protecting group. |
Identificador | |
Publicador |
Wiley - V C H Verlag GmbH & Co. KGaA |
Relação |
DOI:10.1002/anie.201105337 Sahoo, Jugal Kishore, Tahir, Muhammad Nawaz, Hoshyargar, Faegheh, Nakhjavan, Bahar, Branscheid, Robert, Kolb, Ute, & Tremel, Wolfgang (2011) Molecular camouflage : making use of protecting groups to control the self-assembly of inorganic janus particles onto metal–chalcogenide nanotubes by Pearson Hardness. Angewandte Chemie International Edition, 50(51), pp. 12271-12275. |
Direitos |
Copyright 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
Fonte |
School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty |
Palavras-Chave | #Janus particles #nanostructures #nanotubes #protecting groups #surface chemistry |
Tipo |
Journal Article |