Poly[μ-aqua-aqua-μ5-(4-nitrobenzoato)-caesium]


Autoria(s): Smith, Graham
Data(s)

2013

Resumo

In the structure of the title complex [Cs(C7H4N2O2)(H2O)2]n, the Cs salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-donors, a bidentate carboxyl (O,O')-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water O-H...Ocarboxyl and water O-H...O(water) hydrogen-bonding interactions.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/70888/

Publicador

Blackwell Munksgaard

Relação

http://eprints.qut.edu.au/70888/1/PNBACS.pdf

DOI:10.1107/S1600536813030638

Smith, Graham (2013) Poly[μ-aqua-aqua-μ5-(4-nitrobenzoato)-caesium]. Acta Crystallographica Section E : Structure Reports Online, 69(12), m664-m665.

Direitos

Copyright 2013 International Union of Crystallography

This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Fonte

School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty

Palavras-Chave #crystal structure #caesium #4-nitrobenzoic acid #coordination polymer #hydrogen bonding
Tipo

Journal Article