Poly-[μ-aqua-μ5-[(2,3,6-trichlorophenyl)acetato)-caesium]
| Data(s) |
2013
|
|---|---|
| Resumo |
In the structure of the title complex [Cs(C8H4Cl3O2)(H2O)]n, the Cs salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate chelate (O:Cl) interaction involving a carboxyl O-atom and an ortho-related ring substituted Cl atom which is also bridging, a triple-bridging carboxyl O-atom and a bridging water molecule. A two-dimensional sheet polymer is generated, lying parallel to (100), within which there are water O---H...O(carboxyl) hydrogen-bonding interactions. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
Blackwell Munksgaard |
| Relação |
http://eprints.qut.edu.au/70886/1/FENACS.PDF DOI:10.1107/S1600536813029395 Smith, Graham (2013) Poly-[μ-aqua-μ5-[(2,3,6-trichlorophenyl)acetato)-caesium]. Acta Crystallographica Section E : Structure Reports Online, 69(12), m628-m628. |
| Direitos |
Copyright 2013 International Union of Crystallography This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| Fonte |
School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty |
| Palavras-Chave | #030606 Structural Chemistry and Spectroscopy #crystal structure #caesium #coordination polymer #hydrogen bonding #fenac |
| Tipo |
Journal Article |
