The lowest singlet and triplet states of the oxyallyl diradical
| Data(s) |
2009
|
|---|---|
| Resumo |
Small S-T splitting : The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
Wiley - VCH Verlag GmbH & Co. KGaA |
| Relação |
http://eprints.qut.edu.au/70682/1/The_Lowest_Singlet_2009.pdf DOI:10.1002/anie.200904417 Ichino, T., Villano, S.M., Gianola, A.J., Goebbert, D.J., Sanov, A., Velarde, L., Blanksby, S.J., Zhou, X., Hrovat, D.A., Borden, W.T., & Carl Lineberger, W. (2009) The lowest singlet and triplet states of the oxyallyl diradical. Angewandte Chemie (International Edition), 48(45), pp. 8509-8511. |
| Palavras-Chave | #Oxyallyl compounds #Photoelectron spectroscopy #Radicals #Reactive intermediates |
| Tipo |
Journal Article |
