Interstellar molecules. Conversion or C3O-. to C3O in the gas phase


Autoria(s): Blanksby, S.J.; Dua, S.; Bowie, J.H.
Data(s)

1999

Resumo

Neutral C3O has been prepared by collision induced neutralisation of the precursor radical anion formed by the reaction C-=C-CO-OEt --> C3O-. +EtO. The similar neutralisaaion reionisation (-NR+) and charge reversal (CR) spectra of C3O-. indicate that the potential surfaces of C3O and C3O+. show favourable vertical Franck-Condon overlap, This suggests that the bond connectivities of anion, neutral and cation C3O are the same. Copyright (C) 1999 John Wiley & Sons, Ltd.

Identificador

http://eprints.qut.edu.au/70658/

Publicador

John Wiley & Sons, Ltd.

Relação

http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1097-0231(19991130)13:22%3C2249::AID-RCM782%3E3.0.CO;2-%23/abstract

Blanksby, S.J., Dua, S., & Bowie, J.H. (1999) Interstellar molecules. Conversion or C3O-. to C3O in the gas phase. Rapid Communications in Mass Spectrometry, 13(22), pp. 2249-2251.

Fonte

Science & Engineering Faculty

Palavras-Chave #tricarbon monoxide #carbon monoxides #radical-anions #negative-ions #spectroscopy #neutrals #spectra #c5o #c4o #c6o
Tipo

Journal Article