Production and isolation of ligated metal(IV)-oxo ions by tandem mass spectrometry
| Data(s) |
2010
|
|---|---|
| Resumo |
High valent metal(IV)-oxo species, \[M(=O)(Melm)(n)(OAc)](+) (M = Mn-Ni, MeIm = 1-methylimidazole, n = 1-2), which are relevant to biology and oxidative catalysis, were produced and isolated in gas-phase reactions of the metal(II) precursor ions \[M(MeIm)(n)(OAc)](+) (M = Mn-Zn, n = 1-3) with ozone. The precursor ions \[M(MeIm)(OAc)](+) and \[M(MeIm)(2)(OAc)](+) were generated via collision-induced dissociation of the corresponding \[M(MeIm)(3)(OAc)](+) ion. The dependence of ozone reactivity on metal and coordination number is discussed. Copyright (C) 2010 John Wiley & Sons, Ltd. |
| Identificador | |
| Publicador |
John Wiley & Sons Ltd. |
| Relação |
DOI:10.1002/rcm.4493 Taylor, I.F., Blanksby, S.J., Colbran, S B., & Willett, G.D. (2010) Production and isolation of ligated metal(IV)-oxo ions by tandem mass spectrometry. Rapid Communications in Mass Spectrometry, 24(8), pp. 1142-1146. |
| Direitos |
Copyright 2010 John Wiley & Sons, Ltd. |
| Fonte |
School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty |
| Palavras-Chave | #2-his-1-carboxylate facial triad #gas-phase #metal-cations #dioxygen #activation #oxidation #ozone #reactivity #catalysis #kinetics #dissociation |
| Tipo |
Journal Article |
