Interstellar molecules : Conversion or C3O-. to C3O in the gas phase


Autoria(s): Blanksby, Stephen J.; Dua, S.; Bowie, J. H.
Data(s)

03/11/1999

Resumo

Neutral C3O has been prepared by collision induced neutralisation of the precursor radical anion formed by the reaction C-=C-CO-OEt --> C3O-. +EtO. . The similar neutralisaaion reionisation (-NR+) and charge reversal (CR) spectra of C3O-. indicate that the potential surfaces of C3O and C3O+. show favourable vertical Franck-Condon overlap, This suggests that the bond connectivities of anion, neutral and cation C3O are the same. Copyright (C) 1999 John Wiley & Sons, Ltd.

Identificador

http://eprints.qut.edu.au/70221/

Publicador

John Wiley & Sons Ltd.

Relação

http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1097-0231(19991130)13:22%3C2249::AID-RCM782%3E3.0.CO;2-%23/pdf

DOI:10.1002/(SICI)1097-0231(19991130)13:22<2249::AID-RCM782>3.0.CO;2-#

Blanksby, Stephen J., Dua, S., & Bowie, J. H. (1999) Interstellar molecules : Conversion or C3O-. to C3O in the gas phase. Rapid Communications in Mass Spectrometry, 13(22), pp. 2249-2251.

Direitos

Copyright 1999 John Wiley & Sons, Ltd.

Fonte

School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty

Palavras-Chave #tricarbon monoxide #carbon monoxides #radical-anions #negative-ions #spectroscopy #neutrals #spectra #c5o #c4o #c6o
Tipo

Journal Article