(Adipato-2O,O')diaqua[bis(pyridin-2-yl-N)amine]cobalt(II) trihydrate


Autoria(s): Setifi, Z.; Setifi, F.; Smith, G.; El-Ghozzi, M.; Rouag, D.-A.; Avignant, D.; Merazig, H.
Data(s)

2013

Resumo

In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octahedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate dipyridyldiamine ligand, two O-atom donors from one of the carboxylate groups of the bidentate chelating adipate ligand and two water molecules. In addition, there are three solvent water molecules which are involved in both intra- and inter-unit O-HO hydrogen-bonding interactions, which together with an amine-water N-HO hydrogen bond produce a three-dimensional framework.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/60470/

Publicador

Blackwell Publishing on behalf of IUCr

Relação

http://eprints.qut.edu.au/60470/1/SZ5.pdf

DOI:10.1107/S1600536813012981

Setifi, Z., Setifi, F., Smith, G., El-Ghozzi, M., Rouag, D.-A., Avignant, D., & Merazig, H. (2013) (Adipato-2O,O')diaqua[bis(pyridin-2-yl-N)amine]cobalt(II) trihydrate. Acta Crystallographica Section E : Structure Reports Online, E69(6), m335-m336.

Direitos

Copyright 2013 International Union of Crystallography

This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Fonte

School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty

Palavras-Chave #030606 Structural Chemistry and Spectroscopy #crystal structure #metal complex #cobalt #adipate complex
Tipo

Journal Article