Microwave synthesis and spectroscopic characterization of manganese oxalate nanocrystals
| Data(s) |
01/06/2013
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| Resumo |
The microwave synthesis of MnC2O4·2H2O nanoparticles was performed through the thermal double decomposition of oxalic acid dihydrate (C2H2O4·2H2O) and Mn(OAc)2·4H2O solutions using a CATA-2R microwave reactor. Structural characterization was performed using X-ray diffraction (XRD), particle size and shape were analyzed using transmission electron microscopy (TEM). The chemical in the structures was investigated using electron paramagnetic resonance (EPR) as well as optical absorption spectra and near-infrared (NIR) spectroscopies. The nanocrystals produced with this method were pure and had a distorted rhombic octahedral structure. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
Elsevier BV |
| Relação |
http://eprints.qut.edu.au/59751/2/59751.pdf DOI:10.1016/j.partic.2012.06.009 Lakshmi Reddy, S., Udayabashkar Reddy, G., Ramasubba Reddy, R., Siva Reddy, G., Frost, Ray L., & Endo, Tamio (2013) Microwave synthesis and spectroscopic characterization of manganese oxalate nanocrystals. Particuology, 11(3), pp. 340-345. |
| Direitos |
Copyright 2012 Elsevier This is the author's version of a work that was accepted for publication in Particuology. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was susbsequently published in Particuology, [Vol. 11, Issue 3, 2013] http://dx.doi.org/10.1016/j.partic.2012.06.009 |
| Fonte |
School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty |
| Palavras-Chave | #030606 Structural Chemistry and Spectroscopy #Manganese oxalate #Lindbergite #Electron paramagnetic resonance #Optical absorption and NIR spectra #Mn(II) #Water fundamentals |
| Tipo |
Journal Article |
