Isopropyl 2,2-bis(4-bromophenyl)-2-hydroxyacetate


Autoria(s): Smith, Graham
Data(s)

2012

Resumo

In the structure of the title compound C17H16Br2O3, which is a restricted commercial acaricide (common name bromopropylate), has two independent and conformationally similar molecules in the asymmetric unit [dihedral angle between the planes of the two phenyl rings in each, 68.7(4) and 77.4(5)deg]. The C-atoms of the isopropyl group of one of the molecules are disordered over two sites with occupancies of 0.638 and 0.362. Minor non-merohedral twinning was also present in the crystal. Intermolecular hydrogen-bonding interactions involving the hydroxy groups and carboxyl O-atom acceptors give separate centrosymmetric homodimers through cyclic hydrogen-bonding motifs [graph set R2/2(10)].

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/54574/

Publicador

Blackwell Munksgaard

Relação

http://eprints.qut.edu.au/54574/1/BRPROP.pdf

DOI:10.1107/S1600536812044571

Smith, Graham (2012) Isopropyl 2,2-bis(4-bromophenyl)-2-hydroxyacetate. Acta Crystallographica Section E: Structure Reports Online, 68(12), o3276-o3276.

Direitos

Copyright 2012 Blackwell Munksgaard

Fonte

School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty

Palavras-Chave #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #crystal structure #bromopropylate #acaricide #hydrogen bonding
Tipo

Journal Article