Isopropyl 2,2-bis(4-bromophenyl)-2-hydroxyacetate
Data(s) |
2012
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Resumo |
In the structure of the title compound C17H16Br2O3, which is a restricted commercial acaricide (common name bromopropylate), has two independent and conformationally similar molecules in the asymmetric unit [dihedral angle between the planes of the two phenyl rings in each, 68.7(4) and 77.4(5)deg]. The C-atoms of the isopropyl group of one of the molecules are disordered over two sites with occupancies of 0.638 and 0.362. Minor non-merohedral twinning was also present in the crystal. Intermolecular hydrogen-bonding interactions involving the hydroxy groups and carboxyl O-atom acceptors give separate centrosymmetric homodimers through cyclic hydrogen-bonding motifs [graph set R2/2(10)]. |
Formato |
application/pdf |
Identificador | |
Publicador |
Blackwell Munksgaard |
Relação |
http://eprints.qut.edu.au/54574/1/BRPROP.pdf DOI:10.1107/S1600536812044571 Smith, Graham (2012) Isopropyl 2,2-bis(4-bromophenyl)-2-hydroxyacetate. Acta Crystallographica Section E: Structure Reports Online, 68(12), o3276-o3276. |
Direitos |
Copyright 2012 Blackwell Munksgaard |
Fonte |
School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty |
Palavras-Chave | #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #crystal structure #bromopropylate #acaricide #hydrogen bonding |
Tipo |
Journal Article |