Poly[mu3-aqua-aqua(mu3-3,5-dinitrobenzoato-kO1:O3:O5)caesium]
| Data(s) |
2012
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|---|---|
| Resumo |
In the structure of the title complex [Cs(C7H3N2O6)(H2O)2]n, the Cs salt of 3,5-dinitrobenzoic acid, the metal complex centres have have irregular CsO8 coordination, comprising two water molecules (one triply bridging, the other monodentate) and four O-donors from two nitro groups and one bridging carboxyl-O donor group from the ligand. Intra-unit O-H...O hydrogen-bonding interactions involving both water molecules are observed in the three-dimensional polymeric complex structure. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
Blackwell Publishing on behalf of IUCr |
| Relação |
http://eprints.qut.edu.au/53501/1/DNBACS.PDF DOI:10.1107/S1600536812037130 Smith, Graham (2012) Poly[mu3-aqua-aqua(mu3-3,5-dinitrobenzoato-kO1:O3:O5)caesium]. Acta Crystallographica. Section E : Structure Reports Online, 68, m1241-m1242. |
| Direitos |
Copyright 2012 Graham Smith This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| Fonte |
School of Chemistry, Physics & Mechanical Engineering; Science & Engineering Faculty |
| Palavras-Chave | #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #crystal structure #caesium #3,5-dinitrobenzoic acid #coordination polymer #hydrogen bonding |
| Tipo |
Journal Article |
