catena-Poly[[diaqualithium]-mu-[rac-cis-(2-carboxycyclohexane-1-carboxylato-kO1:O2]]
Data(s) |
01/12/2011
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Resumo |
In the structure of the title compound, [C8H11LiO4(H2O)2]n the distorted tetrahadral LiO4 coordination sphere comprises two water molecules and two carboxyl O-donors from separate bridging cis-2-carboxycyclohexane-1-carboxylate monoanions [Li-O range, 1.887(4)-1.946(3)A], giving chain substructures which extend along (010). Water-water and water-carboxyl O-H...O hydrogen bonds stabilize these chain structures and provide inter-chain links, resulting in a two-dimensional layered structure extending across (011). |
Formato |
application/pdf |
Identificador | |
Publicador |
International Union of Crystallography (IUCr) |
Relação |
http://eprints.qut.edu.au/46959/1/CHDCLI.PDF DOI:10.1107/S1600536811045077 Smith, Graham, Wermuth, Urs D., & Williams, Michael L. (2011) catena-Poly[[diaqualithium]-mu-[rac-cis-(2-carboxycyclohexane-1-carboxylato-kO1:O2]]. Acta Crystallographica Section E : Structure Reports Online, 67(12), m1658-m1658. |
Direitos |
Copyright 2011 please consult author |
Fonte |
Chemistry; Faculty of Science and Technology |
Palavras-Chave | #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #crystal structure #hydrogen-bonding #metal complex #lithium |
Tipo |
Journal Article |