Raman spectroscopy of the multi-anion mineral mallestigite Pb3Sb5+(SO4)(AsO4)(OH)6•3H2O – a mineral of archaeological significance
| Data(s) |
01/11/2011
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| Resumo |
Some minerals are formed which show poorly defined X-ray diffraction patterns. Vibrational spectroscopy offers one of the few methods for the assessment of the structure of the oxyanions in such minerals. Among this group of minerals is mallestigite with formula Pb3Sb5+(SO4)(AsO4)(OH)6•3H2O. The objective of this research is to determine the molecular structure of the mineral mallestigite using vibrational spectroscopy. Raman and infrared bands are attributed to the AsO43- , SO42- and water stretching vibrations. Mallestigite is a mineral formed in ancient waste dumps such as occurs at Mallestiger, Carinthia, Austria and as such is a mineral of archaeological significance. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
Elsevier |
| Relação |
http://eprints.qut.edu.au/46411/2/46411.pdf DOI:10.1016/j.saa.2011.08.058 Frost, Ray L., Palmer, Sara J., Xi, Yunfei, & Tan, Keqin (2011) Raman spectroscopy of the multi-anion mineral mallestigite Pb3Sb5+(SO4)(AsO4)(OH)6•3H2O – a mineral of archaeological significance. Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy, 83(1), pp. 432-436. |
| Direitos |
Copyright 2011 Elsevier. This is the author’s version of a work that was accepted for publication in Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy, [83, 1, (2011)] DOI: 10.1016/j.saa.2011.08.058 |
| Fonte |
Chemistry; Faculty of Science and Technology |
| Palavras-Chave | #030606 Structural Chemistry and Spectroscopy #Raman spectroscopy, mallestigite, arsenate, sulphate, archaeology |
| Tipo |
Journal Article |
