Diels-Alder reactions as an efficient route to high purity cyclic polymers
Data(s) |
2011
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Resumo |
A simple and efficient route for the synthesis of cyclic polymer systems is presented. Linear furan protected α-maleimide-ω-cyclopentadienyl functionalized precursors (poly(methyl methacrylate) and poly(tert-butyl acrylate)) were synthesized via atom transfer radical polymerization (ATRP) and subsequent substitution of the bromine end-group with cyclopentadiene. Upon heating at high dilution, deprotection of the dieneophile occurs followed by an intramolecular Diels–Alder reaction yielding a high purity cyclic product. |
Identificador | |
Publicador |
John Wiley & Sons |
Relação |
DOI:10.1002/marc.201100094 Glassner, Mathias, Blinco, James P., & Barner-Kowollik, Christopher (2011) Diels-Alder reactions as an efficient route to high purity cyclic polymers. Macromolecular Rapid Communications, 32(9-10), pp. 724-728. |
Fonte |
Chemistry; Faculty of Science and Technology |
Palavras-Chave | #030300 MACROMOLECULAR AND MATERIALS CHEMISTRY #030306 Synthesis of Materials #atom transfer radical polymerization;cyclic polymers;Diels–Alder reactions |
Tipo |
Journal Article |