[P,P-Di-tert-butyl-N-trimethylsilyl- P-(trimethylsilylamino)phosphineimidato-N,N]bis(pyridine-N)- lithium(I)
| Data(s) |
21/03/2002
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|---|---|
| Resumo |
In the title compound, [Li(C14H36N2PSi2)(C5H5N)2], the bulky chelating monoanionic P,P-di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidate ligand and two pyridine ligands bind to Li in a pseudo-tetrahedral arrangement with twofold symmetry. The Li-N [phosphine]distance is 2.048 (5) Å, while the LiP distance is 2.520 (6) Å |
| Identificador | |
| Publicador |
International Union of Crystallography (IUCr) |
| Relação |
DOI:10.1107/S0108270102002706 Schultz, Madeleine, Straub, Bernd, & Hofmann, Peter (2002) [P,P-Di-tert-butyl-N-trimethylsilyl- P-(trimethylsilylamino)phosphineimidato-N,N]bis(pyridine-N)- lithium(I). Acta Crystallographica, Section C, C58, m256-m257. |
| Fonte |
Faculty of Science and Technology |
| Palavras-Chave | #030204 Main Group Metal Chemistry #imidate ligand #lithium complex #crystal structure |
| Tipo |
Journal Article |
