Halogen bonding between an isoindoline nitroxide and 1,4-diiodotetrafluorobenzene: new tools and tectons for self-assembling organic spin systems


Autoria(s): Hanson, Graeme; Jensen, Paul; McMurtrie, John; Rintoul, Llew; Micallef, Aaron
Data(s)

2009

Resumo

Halogen bonding has been observed for the first time between an isoindoline nitroxide and an iodoperfluorocarbon (see figure), which cocrystallize to form a discrete 2:1 supramolecular compound in which NO.⋅⋅⋅I halogen bonding is the dominant intermolecular interaction. This illustrates the potential use of halogen bonding and isoindoline nitroxide tectons for the assembly of organic spin systems...

Identificador

http://eprints.qut.edu.au/42960/

Publicador

Wiley - V C H Verlag GmbH & Co. KGaA

Relação

DOI:10.1002/chem.200801920

Hanson, Graeme, Jensen, Paul, McMurtrie, John, Rintoul, Llew, & Micallef, Aaron (2009) Halogen bonding between an isoindoline nitroxide and 1,4-diiodotetrafluorobenzene: new tools and tectons for self-assembling organic spin systems. Chemistry: A European Journal, 15(16), pp. 4156-4164.

Fonte

Faculty of Science and Technology; Science & Engineering Faculty

Palavras-Chave #030606 Structural Chemistry and Spectroscopy #Halogen Bonding, Organic Spin System, Nitroxides, Non-covalent Interactions, Radicals
Tipo

Journal Article