Organometallic macrocyclic chemistry. 8.(1) : an unusual metallacycle derived from phosphine−alkynyl thioether coupling
| Data(s) |
01/11/2010
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|---|---|
| Resumo |
The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6 to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3){κ4C,S,S′,S′′-S(C≡CMe)C2H4SC2H4SC(PPh3)CMe}]PF6 arising from the activation of one alkynyl group toward nucleophilic attack by extraneous phosphine. |
| Identificador | |
| Publicador |
American Chemical Society |
| Relação |
DOI:10.1021/om100835r Hill, Anthony F., Niess, Barbara, Schultz, Madeleine, White, Andrew J., & Williams, David J. (2010) Organometallic macrocyclic chemistry. 8.(1) : an unusual metallacycle derived from phosphine−alkynyl thioether coupling. Organometallics, 29(23), pp. 6488-6492. |
| Direitos |
Copyright 2010 American Chemical Society |
| Fonte |
Chemistry; Faculty of Science and Technology |
| Palavras-Chave | #039904 Organometallic Chemistry #ruthenium #metallacycle #alkyne cleavage |
| Tipo |
Journal Article |
