Ethane-1,2-diaminium 4,5-dichlorophthalate


Autoria(s): Smith, Graham; Wermuth, Urs D.
Data(s)

01/01/2010

Resumo

In the structure of the title compound, C2H10N22+·C8H2Cl2O42-, the dications and dianions form hydrogen-bonded ribbon substructures which enclose conjoint cyclic R21(7), R12(7) and R42(8) associations and extend down the c-axis direction. These ribbons inter-associate down b, giving a two-dimensional sheet structure. In the dianions, one of the carboxylate groups is essentially coplanar with the benzene ring, while the other is normal to it [C-C-C-O torsion angles = 177.67 (12) and 81.94 (17)°, respectively].

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/31036/

Publicador

Wiley-Blackwell Munksgaard

Relação

http://eprints.qut.edu.au/31036/1/c31036.pdf

DOI:10.1107/S1600536809054427

Smith, Graham & Wermuth, Urs D. (2010) Ethane-1,2-diaminium 4,5-dichlorophthalate. Acta Crystallographica Section E : Structure Reports Online, 66(1), o235.

Direitos

Copyright 2010 International Union of Crystallography

This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Fonte

Chemistry; Faculty of Science and Technology

Palavras-Chave #030606 Structural Chemistry and Spectroscopy #crystal structure #hydrogen bonding #proton-transfer compounds #4,5-dichlorophthalic acid
Tipo

Journal Article