Raman spectroscopic study of the uranyl mineral metauranospinite Ca[(UO2)(AsO4)]2.8H2O


Autoria(s): Frost, Ray L.; Keeffe, Eloise C.; Cejka, Jiri; Sejkora, Jiri
Data(s)

15/12/2009

Resumo

Raman spectra of metauranospinite Ca[(UO2)(AsO4)]2.8H2O complemented with infrared spectra were studied. Observed bands were assigned to the stretching and bending vibrations of (UO2)2+ and (AsO4)3- units and of water molecules. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were calculated from the Raman and infrared spectra.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/29363/

Publicador

John Wiley & Sons

Relação

http://eprints.qut.edu.au/29363/1/c29363.pdf

DOI:10.1002/jrs.2242

Frost, Ray L., Keeffe, Eloise C., Cejka, Jiri, & Sejkora, Jiri (2009) Raman spectroscopic study of the uranyl mineral metauranospinite Ca[(UO2)(AsO4)]2.8H2O. Journal of Raman Spectroscopy, 40(12), pp. 1786-1790.

Direitos

Copyright 2009 John Wiley & Sons, Ltd.

The definitive version is available at www3.interscience.wiley.com

Fonte

Faculty of Science and Technology; School of Physical & Chemical Sciences

Palavras-Chave #030603 Colloid and Surface Chemistry #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #030606 Structural Chemistry and Spectroscopy #metauranospinite, mineral, uranyl, arsenate, molecular water, Raman, infrared, spectroscopy
Tipo

Journal Article