Raman spectroscopic study of the uranyl sulphate mineral jáchymovite (UO2)8(SO4)(OH)14•13H2O
| Data(s) |
01/11/2009
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| Resumo |
Raman spectra of jáchymovite, (UO2)8(SO4)(OH)14•13H2O, were studied, complemented with infrared spectra, and compared with published Raman and infrared spectra of uranopilite, [(UO2)6(SO4)O2(OH)6(H2O)6] •6H2O. Bands related to the stretching and bending vibrations of (UO2)2+, (SO4)2-, (OH)- and water molecules were assigned. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were calculated from the Raman and infrared spectra. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
John Wiley & Sons |
| Relação |
http://eprints.qut.edu.au/28595/1/c28595.pdf DOI:10.1002/jrs.2227 Frost, Ray L., Cejka, Jiri, Keeffe, Eloise C., & Sejkora, Jiri (2009) Raman spectroscopic study of the uranyl sulphate mineral jáchymovite (UO2)8(SO4)(OH)14•13H2O. Journal of Raman Spectroscopy, 40(11), pp. 1464-1468. |
| Direitos |
Copyright © 2009 John Wiley & Sons, Ltd. The definitive version is available at www3.interscience.wiley.com |
| Fonte |
Faculty of Science and Technology; School of Physical & Chemical Sciences |
| Palavras-Chave | #030603 Colloid and Surface Chemistry #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #030606 Structural Chemistry and Spectroscopy #jáchymovite, uranyl, sulphate, #U-O bond lengths, #O-H…O hydrogen bond lengths #Raman spectroscopy, #infrared spectroscopy, |
| Tipo |
Journal Article |
