Raman spectroscopic study of the uranyl mineral natrouranospinite (Na2,Ca)[(UO2)(AsO4)]2•5H2O


Autoria(s): Frost, Ray L.; Cejka, Jiri; Keeffe, Eloise C.; Sejkora, Jiri
Data(s)

12/11/2009

Resumo

Raman spectra of natrouranospinite complemented with infrared spectra were studied and related to the structure of the mineral. Observed bands were assigned to the stretching and bending vibrations of (UO2)2+ and (AsO4)3- units and of water molecules. U-O bond lengths in uranyl and O-H…O hydrogen bond lengths were calculated from the Raman and infrared spectra.

Formato

application/pdf

Identificador

http://eprints.qut.edu.au/28594/

Publicador

John Wiley & Sons

Relação

http://eprints.qut.edu.au/28594/1/c28594.pdf

DOI:10.1002/jrs.2233

Frost, Ray L., Cejka, Jiri, Keeffe, Eloise C., & Sejkora, Jiri (2009) Raman spectroscopic study of the uranyl mineral natrouranospinite (Na2,Ca)[(UO2)(AsO4)]2•5H2O. Journal of Raman Spectroscopy, 40(11), pp. 1521-1526.

Direitos

Copyright © 2009 John Wiley & Sons, Ltd.

The definitive version is available at www3.interscience.wiley.com

Fonte

Faculty of Science and Technology; School of Physical & Chemical Sciences

Palavras-Chave #030603 Colloid and Surface Chemistry #030600 PHYSICAL CHEMISTRY (INCL. STRUCTURAL) #030606 Structural Chemistry and Spectroscopy #natrouranopinite, mineral, #Raman, #uranyl, arsenate, #infrared, spectroscopy #molecular water,
Tipo

Journal Article