Sodium 2-nitrocinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer
| Data(s) |
2009
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|---|---|
| Resumo |
The title compound catena-poly[aqua-mu3-2-nitrocinnamato], [Na(C9H6NO4)(H2O)2]n, the sodium salt of trans-2-nitrocinnamic acid, is a one-dimensional coordination polymer based on six-coordinate octahedral NaO6 centres comprising three facially-related monodentate carboxylate O-atom donors from separate ligands (all bridging)[Na-O, 2.4370(13)-2.5046(13)A] and three water molecules (two bridging, one monodentate) [Na-O, 2.3782(13)-2.4404(17)A]. The structure is also stabilized by intra-chain water-O-H...O(carboxylate) and O-H...O(nitro) hydrogen bonds. |
| Formato |
application/pdf |
| Identificador | |
| Publicador |
Blackwell Publishing |
| Relação |
http://eprints.qut.edu.au/27836/1/c27836pdf.pdf DOI:10.1107/S1600536809030402 Smith, Graham & Wermuth, Urs D. (2009) Sodium 2-nitrocinnamate dihydrate: a one-dimensional hydrogen-bonded coordination polymer. Acta Crystallographica Section E, 65, m1048. |
| Direitos |
Copyright 2009 Blackwell Publishing and the authors. The definitive version is available at www.blackwell-synergy.com |
| Fonte |
Faculty of Science and Technology; School of Physical & Chemical Sciences |
| Palavras-Chave | #030606 Structural Chemistry and Spectroscopy #crystal structure #coordination polymer #trans-2-nitrocinnamic acid #hydrogen bonding |
| Tipo |
Journal Article |
