Temperature effect on hydrocarbon-enhanced nitric oxide conversion using a dielectric barrier discharge reactor

Experimental investigations into the effect of temperature on conversion of NO in the presence of hydrocarbons (ethylene, acetylene and n-hexane) are presented. An AC energized dielectric barrier discharge reactor was used as the plasma reactor. The experiments were carried out at different temperatures up to 200 degreesC. The discharge powers were measured at all the temperatures. The discharge power was found to increase with temperature. NO conversion in the presence of ethylene and n-hexane was better than that of acetylene at all temperatures. The addition of acetylene at room temperature showed no better conversion of NO compared to no additive case. While at higher temperatures, it could enhance the conversion of NO. A slight enhancement in NO and NOx removal was observed in the presence of water vapor. (C) 2003 Elsevier Science B.V. All rights reserved.

DeNOx Study in Diesel Engine Exhaust Using Barrier Discharge Corona Assisted by V2O5/TiO2 Catalyst

A plasma-assisted catalytic reactor was used to remove nitrogen oxides (NOx) from diesel engine exhaust operated under different load conditions. Initial studies were focused on plasma reactor (a dielectric barrier discharge reactor) treatment of diesel exhaust at various temperatures. The nitric oxide (NO) removal efficiency was lowered when high temperature exhaust was treated using plasma reactor. Also, NO removal efficiency decreased when 45% load exhaust was treated. Studies were then made with plasma reactor combined with a catalytic reactor consisting of a selective catalytic reduction (SCR) catalyst, V2O5/TiO2. Ammonia was used as a reducing agent for SCR process in a ratio of 1:1 to NOx. The studies were focused on temperatures of the SCR catalytic reactor below 200°C. The plasma-assisted catalytic reactor was operated well to remove NOx under no-load and load conditions. For an energy input of 96 J/l, the NOx removal efficiencies obtained under no-load and load conditions were 90% and 72% respectively at an exhaust temperature of 100°C.

Enhanced Performance of Discharge Plasma in Raw Engine Exhaust Treatment-Operation under Different Temperatures and Loads

This paper reports improved performance of discharge plasma in raw engine exhaust treatment. For the purpose of investigation, both filtered and raw diesel engine exhaust were separately treated by the discharge plasma. In raw exhaust environment, the discharge plasma exhibits a superior performance with regard to NOx removal, energy consumption and formation of by-products. In this study, experiments were conducted at conditions of different temperatures and loads.

Treatment of NOx from Diesel Engine Exhaust by Dielectric Barrier Discharge Method

This paper reports improved performance of discharge plasma in filtered engine exhaust treatment. Our paper deals about the removal of NOX emissions from the diesel exhaust by electric discharge plasma. For the treatment of diesel exhaust a new type of reactor referred to as crossflow dielectric barrier discharge reactor has been used, where the gas flow is perpendicular to the corona electrode. Experiments were conducted at different flow rates ranging from 2 l/min to 10 l/min. The discharge plasma assisted barrier discharge reactor has shown promising results in NOX removal at high flow rates.

Application of Solar Powered High Voltage Discharge Plasma for NOX Removal in Diesel Engine Exhaust

This paper proposes a compact electric discharge plasma source for controlling NOX emission in diesel engine exhaust. Boost converter is used to boost to solar powered battery voltage to 24V, further an automobile ignition coil was used to generate the high voltage pulse using fly-back topology. This design is aimed at retrofitting the existing catalytic converters with pulse assisted cleaning technique. In this paper we bring out a relative comparison of discharge plasma and plasma-adsorbent process at different gas flow rates. Activated alumina was used as adsorbent. The main emphasis is laid on the development of a compact pulse source from 12V battery, which is powered by the solar, for the removal of NOX from the filtered diesel engine exhaust.

Application of Pulsed Discharge Plasma For Methanol Synthesis

Synthesis of methanol using pulsed discharge plasma process is gaining significance. We report the production of methanol from methane and CO2/H2O, using pulsed discharge. Experiments were conducted at very low temperature (-192°C) in addition to normal room temperature. Two types of plasma reactors, cylindrical and rectangular, were tested for methanol production with different corona electrodes (straight wire, helical wire and barbed plate). Gas analysis was carried out by GC-MS and the yield of methanol at various operating conditions was compared and discussed. Experiments were carefully conducted laboratory environment

Application of Solar Powered High Voltage Discharge Plasma for NOX Rem

This paper proposes a compact electric discharge plasma source for controlling NOX emission in diesel engine exhaust. Boost converter is used to boost to solar powered battery voltage to 24V, further an automobile ignition coil was used to generate the high voltage pulse using fly-back topology. This design is aimed at retrofitting the existing catalytic converters with pulse assisted cleaning technique. In this paper we bring out a relative comparison of discharge plasma and plasma-adsorbent process at different gas flow rates. Activated alumina was used as adsorbent. The main emphasis is laid on the development of a compact pulse source from 12V battery, which is powered by the solar, for the removal of NOX from the filtered diesel engine exhaust.

Treatment of NOx from Diesel Engine Exhaust by Dielectric Barrier Discharge Method

This paper reports improved performance of advantages when compared to its counterpart as it is cost discharge plasma in filtered engine exhaust treatment. Our effective, low capital and operation costs, salable by- paper deals about the removal of NOX emissions from the diesel products, and integration with the existing systems. In this exhaust by electric discharge plasma. For the treatment of diesel paper we describe an alternate reactor geometry referred to exhaust a new type of reactor referred to as cross-flow dielectric as cross-flow DBD reactor, where the exhaust gas flow barrier discharge reactor has been used, where the gas flow is perpendicular to the wire-cylinder reaction chamber. This perpendicular to the corona electrode. Experiments were reactor is used to treat the actual exhaust of a 3.75 kW diesel- conducted at different flow rates ranging from 2 l/min to 10 l/ generator set. The main emphasis is laid on the NOX treatment min. The discharge plasma assisted barrier discharge reactor of diesel engine exhaust. Experiments were carried out at has shown promising results in NOX removal at high flow rates.

A core study on NOX removal in diesel exhaust by pulsed/ac/dc electric discharge plasma

In this paper a study on effect of different energization on removal of NOX in diesel engine exhaust has been presented. Here we made a detailed qualitative study of effect of pulsed/ac/dc voltage energizations on the NOX treatment of using conventional wire-cylinder reactor configuration. It was observed that amongst different energizations, pulse energization exhibits maximum NOX removal efficiency when compared to ac and dc energizations. For a given specific energy density, wire-cylinder reactor filled with BaTiO3 pellet gives higher NOX removal efficiency when compared to reactor without pellets under both pulse and ac energization. The dc energization does not have much impact on the removal processes. The paper further discusses the individual energization cases in detail.

Dielectric Barrier Discharge Cascaded with Red Mud Waste to Enhance NOX Removal from Diesel Engine Exhaust

Red mud is a waste by-product generated during the processing of bauxite, the most common ore of aluminium. With the presence of ferric oxide, high surface area, resistance to poisoning and low cost, red mud made itself a good alternative to the existing commercial automobile catalyst. The cascading of dielectric barrier discharge plasma with red mud improved the NOX removal from diesel engine exhaust significantly. The DeNO(X) efficiency with discharge plasma was 74% and that with red mud was 31%. The efficiency increased to 92% when plasma was cascaded with red mud catalyst operating at a temperature of 400 degrees C. The NOX removal was dominated by NO2 removal. The studies were conducted at different temperatures and the results were discussed.

Simulating the daily discharge of the Mandovi River, west coast of India

A hydrological modelling framework was assembled to simulate the daily discharge of the Mandovi River on the Indian west coast. Approximately 90% of the west-coast rainfall, and therefore discharge, occurs during the summer monsoon (June-September), with a peak during July-August. The modelling framework consisted of a digital elevation model (DEM) called GLOBE, a hydrological routing algorithm, the Terrestrial Hydrological Model with Biogeochemistry (THMB), an algorithm to map the rainfall recorded by sparse rain-gauges to the model grid, and a modified Soil Conservation Service Curve Number (SCS-CN) method. A series of discharge simulations (with and without the SCS method) was carried out. The best simulation was obtained after incorporating spatio-temporal variability in the SCS parameters, which was achieved by an objective division of the season into five regimes: the lean season, monsoon onset, peak monsoon, end-monsoon, and post-monsoon. A novel attempt was made to incorporate objectively the different regimes encountered before, during and after the Indian monsoon, into a hydrological modelling framework. The strength of our method lies in the low demand it makes on hydrological data. Apart from information on the average soil type in a region, the entire parameterization is built on the basis of the rainfall that is used to force the model. That the model does not need to be calibrated separately for each river is important, because most of the Indian west-coast basins are ungauged. Hence, even though the model has been validated only for the Mandovi basin, its potential region of application is considerable. In the context of the Prediction in Ungauged Basins (PUB) framework, the potential of the proposed approach is significant, because the discharge of these (ungauged) rivers into the eastern Arabian Sea is not small, making them an important element of the local climate system.

Ganga-Brahmaputra river discharge from Jason-2 radar altimetry: An update to the long-term satellite-derived estimates of continental freshwater forcing flux into the Bay of Bengal

This paper discusses the use of Jason-2 radar altimeter measurements to estimate the Ganga-Brahmaputra surface freshwater flux into the Bay of Bengal for the period mid-2008 to December 2011. A previous estimate was generated for 1993-2008 using TOPEX-Poseidon, ERS-2 and ENVISAT, and is now extended using Jason-2. To take full advantages of the new availability of in situ rating curves, the processing scheme is adapted and the adjustments of the methodology are discussed here. First, using a large sample of in situ river height measurements, we estimate the standard error of Jason-2-derived water levels over the Ganga and the Brahmaputra to be respectively of 0.28 m and 0.19 m, or less than similar to 4% of the annual peak-to-peak variations of these two rivers. Using the in situ rating curves between water levels and river discharges, we show that Jason-2 accurately infers Ganga and Brahmaputra instantaneous discharges for 2008-2011 with mean errors ranging from similar to 2180 m(3)/s (6.5%) over the Brahmaputra to similar to 1458 m(3)/s (13%) over the Ganga. The combined Ganga-Brahmaputra monthly discharges meet the requirements of acceptable accuracy (15-20%) with a mean error of similar to 16% for 2009-2011 and similar to 17% for 1993-2011. The Ganga-Brahmaputra monthly discharge at the river mouths is then presented, showing a marked interannual variability with a standard deviation of similar to 12500 m(3)/s, much larger than the data set uncertainty. Finally, using in situ sea surface salinity observations, we illustrate the possible impact of extreme continental freshwater discharge event on the northern Bay of Bengal as observed in 2008.