Stable isotope composition of carbonate components of Rhaetian shallow-water limestones of the Wombat Plateau

Stable oxygen- and carbon-isotope ratios of Rhaetian (upper Triassic) limestone samples from the Wombat Plateau, northwest Australia, were measured to explore possible diagenetic pathways that the material underwent after deposition in a shallow-water environment, before plateau submergence in the Early Cretaceous. Host sediment isotopic values cluster near typical marine carbonate values (d18O ranging from -2.57 per mil to +1.78 per mil and d13C, from +2.45 per mil to +4.01 per mil). Isotopic values of equant clear calcite lining or filling rock pores also plot in the field of marine cements (d18O = +1.59 per mil to -2.24 per mil and d13C = +4.25 per mil to +2.57 per mil), while isotopic values for neomorphic calcites replacing skeletal (megalodontid shell) carbonate material show a wider scatter of oxygen and carbon values, d18O ranging from +2.73 per milo to -6.2 per mil and d13C, from +5.04 per mil to +1.22 per mil. Selective dissolution of metastable carbonate phases (aragonite?) and neomorphic replacement of skeletal material probably occurred in a meteoric phreatic environment, although replacement products (inclusion-rich microspar, clear neomorphic spar, etc.) retained the original marine isotopic signature because transformation probably occurred in a closed system dominated by the composition of the dissolving phases (high rock/water ratio). The precipitation of late-stage equant (low-Mg?) calcite cement in the pores occurred in the presence of normal marine waters, probably in a deep-water environment, after plateau drowning. Covariance of d18O and d13C toward negative values indeed suggests influence of meteorically modified fluids. However, none of the samples shows negative carbon values, excluding the persistence of organic-rich soils on subaerial karstic surfaces (Caribbean-style diagenesis). Petrographical and geochemical data are consistent with the sedimentological evidence of plateau drowning in post-Rhaetian times and with a submarine origin of the >70-m.y.-long Jurassic hiatus.

Upper Triassic nannofossils from Wombat Plateau, Northwest Australia

A taxonomic and biostratigraphic investigation has been carried out on Upper Triassic (Carnian-Rhaetian) nannofossils from Sites 759, 760, 761 and 764 drilled on the Wombat Plateau during ODP Leg 122. The recovery of continuous sequences containing well preserved nannofossils has enabled us to refine the previous taxonomy and biostratigraphy of this interval. Fossil assemblages are of two major types: (1) previously described calcareous taxa were recovered at Sites 761 and 764; and (2) sideritic forms, which may represent diagenetic replacement of calcareous nannofossils, were observed in material from Sites 759 and 760. The sideritic forms proved difficult to study taxonomically due to inadequate optical properties. Calcareous nannofossil assemblages in the Upper Triassic are dominated by Prinsiosphaera triassica. We show that the multitude of identities of this species in the light microscope are the result of selective etching on a layered structure. We propose an evolutionary lineage for the earliest known coccoliths, with Crucirhabdus primulus as the ancestor. This species gave rise to C. minutus and Archaeozygodiscus koessenensis. The Upper Triassic can be subdivided based on the sequential first occurrences of C. primulus and Eoconusphaera zlambachensis in the upper Norian. The late Norian and Rhaetian were times of slow evolution of calcareous nannofossils. However, we noted three morphometric changes in this time-interval which possess biostratigraphic utility: (1) P. triassica increases in diameter from an average of 6 µm to over 9 µm; (2) E. zlambachensis evolves from a stubby to an elongated shape; and (3) C. primulus increases in size. Upper Triassic assemblages from the Wombat Plateau are similar in composition and diversity to those which have been described in detail from the Alps. In both areas, nannofossiliferous sediments interfinger with massive limestones deposited in reef and peri-platform environments. Stable isotopic analyses of Wombat Plateau nannofossil assemblages indicate that they thrived in open ocean conditions. Biostratigraphy allows sequence chronostratigraphic interpretation of ODP Site 761 and supports the chronostratigraphic cycle charts of Haq et al. (1987).

Composition of Carnian to Norian sandstones from the Wombat Plateau (Table 1)

The Carnian to Norian sediments, as much as 600 m in total thickness, recovered from ODP Sites 759 and 760 on the Wombat Plateau, are generally represented by fluvial-dominated deltaic successions. In general, the Carnian to Norian sandstones are quartzose. The average ratio of monocrystalline quartz grains, total feldspar grains, and total lithic fragments (i.e., Qm:F:Lt ratio) is 71:22:7. This indicates that they were derived mainly from the transitional continental and cratonic interior provenance terranes, such as the Pilbara Precambrian block to the south of the Wombat Plateau. The upper Carnian sediments, however, are characterized by more feldspathic sandstone petrofacies. They typically contain some volcanic rock fragments with trachytic texture and indicate the onset of the incipient rift-related tectonic movement, such as uplift and subsequent abrupt basin subsidence, together with volcanism in the Gondwana continental block. Mixed siliciclastic and carbonate cycles are typically intercalated in the prodelta to delta front deposits that developed mainly in a lagoon-like, restricted marine environment. The restricted marine environment developed during transgressions as the outflow of shallow water was restricted by depositional barriers. Around the barriers and/or delta lobes, carbonate shoals/banks were probably developed and the allochemical components of the neritic limestones may have been transported into the restricted marine environment by overwash processes and/or storm waves. Siliciclastic detritus, on the other hand, was mainly derived accompanied by delta progradation dominated by fluvial processes in the restricted marine environment. Therefore, we interpret the mixed siliciclastic and carbonate cycles in the deltaic successions to be a result of transgression-regression cycles in a deltaic system during the Late Triassic.

Petrography and geochemistry of organic matter in Triassic and Cretaceous sediments from the Wombat and Exmouth Plateau

Triassic (Carnian-Rhaetian) continental margin sediments from the Wombat Plateau off northwest Australia (Sites 759, 760, 761, and 764) contain mainly detrital organic matter of terrestrial higher plant origin. Although deposited in a nearshore deltaic environment, little liptinitic material was preserved. The dominant vitrinites and inertinites are hydrogen-lean, and the small quantities of extractable bitumen contain w-alkanes and bacterial hopanoid hydrocarbons as the most dominant single gas-chromatography-amenable compounds. Lower Cretaceous sediments on the central Exmouth Plateau (Sites 762 and 763) farther south in general have an organic matter composition similar to that in the Wombat Plateau sediments with the exception of a smaller particle size of vitrinites and inertinites, indicating more distal transport and probably deposition in deeper water. Nevertheless, organic matter preservation is slightly better than in the Triassic sediments. Long-chain fatty acids, as well as aliphatic ketones and alcohols, are common constituents in the Lower Cretaceous sediments in addition to n-alkanes and hopanoid hydrocarbons. Thin, black shale layers at the Cenomanian/Turonian boundary, although present at several sites (Sites 762 and 763 on the Exmouth Plateau, Site 765 in the Argo Abyssal Plain, and Site 766 on the continental margin of the Gascoyne Abyssal Plain), are particularly enriched in organic matter only at Site 763 (up to 26%). These organic-matter-rich layers contain mainly bituminite of probable fecal-pellet origin. Considering the high organic carbon content, the moderate hydrogen indices of 350-450 milligrams of hydrocarbon-type material per gram of Corg, the maceral composition, and the low sedimentation rates in the middle Cretaceous, we suggest that these black shales were accumulated in an area of oxygen-depleted bottom-water mass (oceanwide reduced circulation?) underlying an oxygen-rich water column (in which most of the primary biomass other than fecal pellets is destroyed) and a zone of relatively high bioproductivity. Differences in organic matter accumulation at the Cenomanian/Turonian boundary at different sites off northwest Australia are ascribed to regional variations in primary bioproductivity.

Late Triassic palynology of the Wombat Plateau, northwestern Australia

Cores from Leg 122, Sites 759, 760, 761, and 764, were sampled at intervals of one sample per 1.5-m section in the Upper Triassic sequences. Spores, pollen, acritarchs, freshwater algae, and dinoflagellate cysts were studied to establish a palynostratigraphic framework for the Late Triassic. The palynological sequence is interpreted in terms of Australian spore-pollen zones: the Carman Samaropollenites speciosus Zone, the Norian Minutosaccus crenulatus Zone, and the Rhaetian Ashmoripollis reducta Zone. The Samaropollenites speciosus Zone-Minutosaccus crenulatus Zone boundary is marked by the change of pollen abundance and has a gradual character. Therefore, a transitional uppermost Carnian to Norian Samaropollenites speciosus/Minutosaccus crenulatus Zone is used. Age-determining dinoflagellate cysts are present in the Norian and Rhaetian sediments.

Neogene planktonic foraminifers from Wombat and Exmouth Plateau

Diverse, warm-water planktonic foraminiferal faunas prevailed on the Wombat and Exmouth plateaus during the Neogene, in spite of the northward drift of Australia across 10° to 15° latitude since the early Miocene. Invasions of cool-water species occurred during periods of global cooling in the late middle Miocene, late Miocene, and Pleistocene, and reflect periods of increased northward transport of cool surface water, probably via the West Australian Current. The sedimentary record of the Neogene on Wombat and Exmouth Plateau is interrupted by two hiatuses (lower Miocene, Zone N5, and upper middle to upper Miocene, Zones N15-N17), and one redeposited section of upper Miocene to uppermost Pliocene sediments. Mechanical erosion or nondeposition by increased deep-water flow or tilting and uplift of Wombat and Exmouth plateaus, resulting in sediment shedding, are the most likely explanations for these Miocene hiatuses, but which of these processes were actually operative on the Wombat and Exmouth plateaus is uncertain. The redeposited section of upper Miocene to uppermost Pliocene sediments in Hole 761B, however, certainly reflects a latest Pliocene period of uplift and tilting of the Wombat Plateau. An important finding was the occurrence of Zone N15-correlative sediments in Hole 762B without any representative of Neogloboquadrina. Similar findings in Java and Jamaica indicate that the earliest spreading of Neogloboquadrina acostaensis in the tropical region resulted from migration. The evolution of this species, therefore, must have taken place in higher latitudes. I suggest that Neogloboquadrina acostaensis evolved from Neogloboquadrina atlantica in the North Atlantic within Zone NN9, but how and where in the region this speciation took place is still uncertain

Geochemistry of ferromanganese deposits from the Wombat Plateau

Ferromanganese crusts, nodules, and ferromanganese-rich sediments were recovered on the Wombat Plateau, northwest Australian continental margin, by dredging during Bureau of Mineral Resources cruise 56 of Rig Seismic and by drilling during ODP Leg 122 of JOWES Resolution. We report here the chemistry and mineralogy of the ferromanganese crusts, nodules, and associated ferromanganese-rich sediments. The ferromanganese deposits from the ODP sites are up to 40 cm thick and probably formed in Late Cretaceous to Eocene times. Those from outcrops usually formed in several phases, and their age is unconstrained except that the substrates are Mesozoic. The samples were recovered from present-day water depths of 2000-4600 m, on the Wombat Plateau adjacent to the Argo Abyssal Plain. Both the nodules and crusts are primarily vernadite (delta-MnO2) and are chemically and mineralogically similar, and not dissimilar from ferromanganese deposits found elsewhere on Australian and other marginal plateaus. They are markedly different from most deep-sea deposits. The only crystalline iron phase identified within the ferromanganese deposits is goethite. Concentrations of metals of potential economic interest are generally low compared to those from vernadite-rich seamount crusts and nodules and from abyssal nodules from areas of high resource potential in the Pacific Ocean. Maximum metal values reach 0.55% Co, 0.58% Ni, and 0.20% Cu in deposits containing 4.8% to 30.9% Fe and 4.4% to 21.1% Mn.

Cretaceous calcareous nannofossils from Exmouth and Wombat Plateau, Northwest Australia

Three sites drilled during Leg 122, Site 761 on the Wombat Plateau and Sites 762 and 763 on the Exmouth Plateau, provide a composite Cretaceous section ranging in age from Berriasian to Maestrichtian. Together, these sites contain an apparently complete, expanded Aptian-Maestrichtian record. Consistently occurring and moderately well-preserved nannofossil assemblages allow reasonably high biostratigraphic resolution. Our data indicate that traditional middle and Upper Cretaceous nannofossil biozonations are not entirely applicable in this region. In this investigation, we compare in detail the relative ranges of key Cretaceous nannofossil markers in the eastern Indian Ocean and in sections from Europe and North Africa. We have determined which previously used events are applicable, and which additional markers have biostratigraphic utility in this region. Significant differences in Campanian-Maestrichtian assemblages exist between the more northern Site 761 and Sites 762 and 763. Such differences are surprising, considering that these sites are only separated by 3° of latitude. We interpret them as marking a strong thermal gradient over the Exmouth Plateau region. Other results include the recovery of an expanded Albian-Cenomanian sequence containing a mixture of Austral and Tethyan floras, which will enable correlation of biozonations established for these two realms; the recovery of two condensed but apparently complete Cenomanian-Turonian boundary sections; correlation of Upper Cretaceous calcareous nannofossil biostratigraphy with magneto- and foraminifer stratigraphy; and correlation of portions of the Barrow Group equivalents to the Berriasian and Valanginian stages.

Cretaceous ostracodes from Wombat and Exmouth Plateau

The Cretaceous ostracodes species recognized on Leg 122 represent elements of South Gondwanan faunistic province. In Lower and middle Cretaceous cores, ostracodes species present were originally described from South Africa and in cores from Deep Sea Drilling Project Leg 36 (Falkland Plateau): Arculicythere tumida, Bythocypris? cf. nodosa, 'Bythocypris' cf. strogylae, Collosaboris? stanleyensis, Cytherella bensoni, Majungaella nematis, Robsoniella cf. falklandensis and Pirileberis aff. mkuzensis. In Upper Cretaceous levels, the Australian species Apateloschizocythere geniculata, Bairdia austracretacea, Cytherella cf. atypica, Cytherella cf. jonesi, Cytherelloidea cf. carnarvonensis, Cytherelloidea cf. colemani, Karsteneis aspericava, and Trachyleberis anteplana were found.

Magnetic properties of Triassic sediments of the Wombat Plateau

During drilling at Sites 759, 760, and 761 of Leg 122 (Exmouth Plateau, northwest Australia), a thick section of Upper Triassic sediments was recovered. Paleomagnetic analyses were made on 398 samples from Holes 759B, 760A, 760B, and 761C. Progressive thermal demagnetization, alternating field demagnetization, or mixed treatment removed an initial unstable component and isolated a characteristic remanent magnetization which is of normal or reversed polarity. The magnetostratigraphic results allow us to propose a magnetic polarity sequence which extends from the upper Carnian to lower Rhaetian. This sequence reveals many more reversals than previously suggested from paleomagnetic studies. The magnetostratigraphic data also allow us to suggest correlations between Sites 759 and 760.