Hybridization of poly(4-vinyl pyridine)-b-polystyrene-b-poly(4-vinyl pyridine) aggregates in dioxane/water solution

Self-assembly of binary blends of two triblock copolymers of poly(4-vinyl pyridine)-b-polystyrene-b-poly(4-vinyl pyridine), i.e., P4VP(43)-b-PS260-b-P4VP(43) (P1) and P4VP(43)-b-PS366-b-P4VP(43) (P2), in dioxane/water solution was studied. These two triblock copolymers individually tend to form vesicles (P2) and cylindrical micelles (P1) in dilute solution. It was found that copolymer components in the blend, sample preparation method, and annealing time had significant effect on hybridization aggregate morphology. By increasing P1 content in the copolymer blends, fraction of looped and stretched cylinders increased, while fraction of bilayers decreased. Nearly no bilayer was observed when P1 content was above 85 wt%.

利用MALDI-TOF质谱技术研究MPEG-b-PCL两嵌段共聚物的嵌段长度及嵌段分布

利用基质辅助激光解吸电离飞行时间质谱(MALDI-TOFMS)结合源后分解(PSD)技术对甲氧基封端的聚乙二醇-b-聚己内酯(MPEG-b-PCL)两嵌段共聚物进行了结构分析.根据得到的MALDI-TOFMS谱图和PSD碎片信息清晰地确定了嵌段共聚物的嵌段长度和嵌段分布.结果表明,采用MALDI-TOFMS结合PSD技术研究这类嵌段共聚物链结构非常有效.这为更好地认识和应用这类嵌段共聚物提供了重要的依据,同时也建立了分析这类嵌段共聚物的方法.

温度敏感性PNIPAM-b-PZLL-b-mPEG三嵌段共聚物的合成与自组装研究

通过大分子引发剂引发ε-苄氧羰基-L-赖氨酸-N-羧酸酐(Lys-NCA)开环聚合和大分子缩合的方法合成了聚(N-异丙基丙烯酰胺)-b-聚(ε-苄氧羰基-L-赖氨酸)-b-聚乙二醇单甲醚三嵌段共聚物(PNIPAM-b-PZLL-b-mPEG).用GPC和1H-NMR对其结构进行了表征.用芘荧光探针法证明了该三嵌段聚合物形成胶束的性质并测定了临界胶束浓度(CMC).动态光散射(DLS)研究表明,在固定PNIPAM-b-PZLL链段长度的情况下,mPEG分子量为2000时,胶束在温度高于临界溶解温度(LCST)时发生聚集,mPEG分子量为5000时,胶束在LCST以上没有发生聚集.

PS-b-P4VP/CoSm杂化材料的制备及其磁性能

用溶液相金属盐沉积法在苯乙烯与4-乙烯基吡啶嵌段共聚物(PS-b-P4VP)胶束中制备了平均直径为12 nm的PS-b-P4VP/Co、PS-b-P4VP/CoSm(nCo∶nSm=3.8∶1,13.0∶1)、PS-b-P4VP/Sm纳米粒子。胶束溶液通过高温回流使磁性成核粒子和磁性金属原子的流动能力和扩散能力提高而获得尺寸均一的颗粒。

齐聚[3,2-b]并二噻吩的合成、表征及其在有机薄膜晶体管中的应用

通过Stille偶联反应合成了5,5″-二辛基-2,2′∶5′2″-三联[3,2-b]并二噻吩,并对该化合物的物理化学性质以及真空蒸镀薄膜的结构和形貌进行了详细表征.以这一化合物作为半导体层、采用顶电极结构制备了有机薄膜晶体管,并对薄膜生长基底温度做了优化,发现基底温度为100℃时器件性能最好,迁移率达到0.13 cm2/V.s,开关比为7×103,阈值电压为-19V.

Dendritic Superstructures and Structure Transitions of Asymmetric Poly(L-lactide-b-ethylene oxide) Diblock Copolymer Thin films

The evolution of morphologies of isothermally crystallized thin films with different thicknesses of poly(L-lactide-bethylene oxide) diblock copolymer was observed by optical microscopy (OM) and atomic force microscopy (AFM). Dendritic superstructures stacked with lamellae were investigated in thin films with similar to 200 nm to similar to 400 nm thickness. The lamellar structure was a lozenge- or truncated-lozenge-shaped single crystal of PLLA confirmed by AFM observations. The contour of the dendritic superstructures is hexagonal, and two types of sectors, [110] and [100], can be classified in terms of the chain-folding and crystal growth directions. These phenomena Are due to the interplay of the crystallization of the PLLA block, the microphase separation of the block copolymer, and the effect of the film thickness.