Functional state observers design for interconnected time-delay systems

His research contributes to the field of functional state estimation for interconnected time-delay systems. Through progressive improvements and refinements, these developed observer structures have practical application for industry and more widely in the engineering field.

Transient stability enhancement of multimachine power systems using nonlinear observer-based excitation controller

This paper presents an approach to design a nonlinear observer-based excitation controller for multimachine power systems to enhance the transient stability. The controller is designed based on the partial feedback linearization of a nonlinear power system model which transforms the model into a reducedorder linear one with an autonomous dynamical part. Then a linear state feedback stabilizing controller is designed for the reduced-order linear power system model using optimal control theory which enhances the stability of the entire system. The states of the feedback stabilizing controller are obtained from the nonlinear observer and the performance of this observer-based controller is independent of the operating points of power systems. The performance of the proposed observer-based controller is compared to that of an exact feedback linearizing observer-based controller and a partial feedback linearizing controller without observer under different operating conditions.

Partial state estimation of time-delay systems.

This thesis broadly studies three crucial and rigorous inter-related control theoretical subjects: (i) Partial state estimation of linear systems; (ii) Stability analysis of time-delay systems with interval time-varying delays; and (iii) Functional observer design for time-delay systems.

Time-Dependent Density Functional Molecular Orbital and Excited State Calculations on Bis(porphyrinyl)butadiynes in the Monocationic, Neutral, Monoanionic, and Dianionic Oxidation States

We report a theoretical study of the multiple oxidation states (1+, 0, 1−, and 2−) of a meso,meso-linked diporphyrin, namely bis[10,15,20-triphenylporphyrinatozinc(II)-5-yl]butadiyne (4), using Time-Dependent Density Functional Theory (TDDFT). The origin of electronic transitions of singlet excited states is discussed in comparison to experimental spectra for the corresponding oxidation states of the close analogue bis{10,15,20-tris[3‘,5‘-di-tert-butylphenyl]porphyrinatozinc(II)-5-yl}butadiyne (3). The latter were measured in previous work under in situ spectroelectrochemical conditions. Excitation energies and orbital compositions of the excited states were obtained for these large delocalized aromatic radicals, which are unique examples of organic mixed-valence systems. The radical cations and anions of butadiyne-bridged diporphyrins such as 3 display characteristic electronic absorption bands in the near-IR region, which have been successfully predicted with use of these computational methods. The radicals are clearly of the “fully delocalized” or Class III type. The key spectral features of the neutral and dianionic states were also reproduced, although due to the large size of these molecules, quantitative agreement of energies with observations is not as good in the blue end of the visible region. The TDDFT calculations are largely in accord with a previous empirical model for the spectra, which was based simplistically on one-electron transitions among the eight key frontier orbitals of the C4 (1,4-butadiyne) linked diporphyrins.