A study of hydrogen bonding in concentrated diol/water solutions by proton NMR correlations with glass formation

Solute/water interactions in a series of diol solutions have been investigated by ¹H NMR. Strong hydrogen bonding between water and alcohols that are more basic than water is thought to result in lower chemical shifts of water protons compared to the case of pure water. This is attributed to a greater degree of covalent character in the hydrogen bonding between water and the more basic diols. The inductive effect of the methyl group and longer chain alkyls is observed to increase basicity in ethylene glycol, propylene glycol, and 2,3-butanediol solutions. A correlation between the glass-forming ability of the diol solutions and the stronger hydrogen-bonding solutes (i.e., stronger bases) is developed, with 2,3-butanediol best promoting glass formation at the lowest concentrations.

Performance of building integrated solar hot water systems

The integration of solar energy systems into buildings has been the subject of considerable commercial and academic research, particularly building integrated photovoltaics. However, the integration of solar hot water systems into roofing systems has had far less attention. This paper presents the theoretical and experimental results of a novel building integrated solar hot water system developed using existing long run roofing materials.

This work shows that it is possible to achieve effective integration that maintains the aesthetics of the building and also provides useful thermal energy. The results of an unglazed 108m2 swimming pool heater and 8m2 glazed domestic hot water systems are presented.

The experimental results show that the glazed system performs close to the theoretical model and is an effective provider of hot water in certain climates. However it was also found that for larger scale building integrated solar water heating systems, special attention must be paid to the configuration and arrangement of the collectors in order to minimise problems with respect to flow distribution and its effect on collector and system efficiency.

Effect of cold plasma pre-treatment on photocatalytic activity of 3D fabric loaded with nano-photocatalysts: response surface methodology

In this study, the physico-chemical effects occasioned by the cold plasma discharge (CPD) on the photo-decolorization of Reactive Orange 16 (RO16) by 3D fabrics (spacer fabrics) loaded with ZnO:TiO2 nano-photocatalysts (nphs) were optimized via response surface methodology (RSM). CPD was employed to improve the surface characteristics of the spacer fabrics for nphs loading. Surface morphology and color variation were studied utilizing scanning electron microscopy (SEM) and CIE-Lab system, respectively. The effect of CPD on the wetting ability of the spacer fabrics was examined using dynamic adsorption measurement (DAM). Also, X-ray fluorescence (XRF) was utilized to investigate the durability of the nphs on the spacer fabrics. All the experiments were implemented in a Box-Behnken design (BBD) with three independent variables (CPD treatment time, dye concentration and irradiation time) in order to optimize the decolorization of RO16. The anticipated values of the decolorization efficiency were found to be in excellent agreement with the experimental values (R2 = 0.9996, Adjusted R2 = 0.9992). The kinetic analysis demonstrated that the photocatalytic decolorization followed the Langmuir-Hinshelwood kinetic model. In conclusion, this heterogeneous photocatalytic process is capable of decolorizing and mineralizing azoic reactive dye in textile wastewater. Moreover, the results confirmed that RSM based on the BBD was a suitable method to optimize the operating conditions of RO16 degradation.

Preparation and characterization of the hydrogen storage activated carbon from coffee shell by microwave irradiation and KOH activation

Coffee shell is an environmental concern to china along with steady growth of coffee production. This study attempt to characterize high specific surface area activated carbon (HSSA-AC). HSSA-AC was prepared from carbonized material which obtained from coffee shell by microwave irradiation. Textural properties and surface chemistry of HSSA-AC were found to be strongly depending on the activation time, KOH/C ratio and particle size. The textural properties of the samples were investigated by means of scanning electron microscope analyzer (SEM), cryogenic N2 adsorption, whereas, surface chemistry was probed through Fourier Transform Infrared (FTIR) spectrometer (Maldhure and Ekhe, 2011) and Hydrogen storage performance was tested by H2 adsorption. Maximum surface area of 3149 m2 g−1, Iodine adsorption value 2566 mg/g, Methylene Blue adsorption value 47.5 mL 0.1 g−1, the hydrogen adsorption value 0.91 wt% at 14 MPa and yield 39% was observed in case of microwave treated sample at activation time 9 min, KOH/C ratio 5 and particle size 0.25–0.71 mm. Results revealed usefulness of microwave treatment in influencing surface area of HSSA-AC which could be used in a hydrogen storage material research application.

Photocatalytic reduction of carbon dioxide

Carbon dioxide reforming happens all the time in nature by photosynthesis of plants. It thus provides a great challenge to equal or surpass this photosynthesis in an artificial system. This paper presents a literature review of using semi-conductor to assist photocatalytic reduction of carbon dioxide under UV irradiation. It analyses some key factors influencing the reaction rates which have been studied worldwide in respective areas. Special interest is taken in recommending possible improvements for the heterogeneous photocatalysis involving gas-solid interfaces, particularly in relation to the influencing factors affecting product concentrations and the reduction rate.

Solar heating systems for recirculation aquaculture

The literature over the past 25 years indicates that there has been a continued interest in using passive and active solar technologies to reduce the conventional energy required to maintain water temperatures in small recirculation aquaculture systems. Although all of the experimental systems reviewed report favourable results, there is little information available to guide system designers. This paper describes the use of a simulation model to predict the annual conventional energy consumption of a 10.6 m3 RAS enclosed in a double layer polyethylene greenhouse in two different climates. The water was maintained at 22.5 °C and the recirculation rate was 10% of tank volume per day. Simple unglazed solar collectors have also been combined with the greenhouse to further reduce energy consumption. The effect of increasing collector area on the solar fraction and utilization of useful energy was predicted. Finally, the model was used to investigate the relationship between the occurrence of condensation on the inner cover, ventilation rates and energy use. It was found that in a hot dry climate, the greenhouse alone was sufficient to reduce the conventional energy requirements by 87%; while in the cooler temperate climate reductions of 66% were possible. When solar collectors were added to the system, conventional energy requirements were reduced further and depended on the area of collector used. For example, in the temperate climate location, conventional energy requirements were reduced to 23% of a RAS enclosed in a non-solar building when 26 m2 of solar collector inclined at the optimum angle for winter energy collection were used. Although condensation could be successfully reduced by ventilation of the greenhouse, this increased conventional energy requirements because the potential for evaporation was increased. Covering the tanks at night was found to be a more effective strategy because it reduced condensation and conventional energy use simultaneously.

Effect of particle size on the photocatalytic activity of nanoparticulate zinc oxide

In this study, a three-stage process consisting of mechanical milling, heat treatment, and washing has been used to manufacture nanoparticulate ZnO powders with a controlled particle size and minimal agglomeration. By varying the temperature of the post-milling heat treatment, it was possible to control the average particle size over the range of 28–57 nm. The photocatalytic activity of these powders was characterized by measuring the hydroxyl radical concentration as a function of irradiation time using the spin-trapping technique with electron paramagnetic resonance spectroscopy. It was found that there exists an optimum particle size of approximately 33 nm for which the photocatalytic activity is maximized. The existence of this optimal particle size is attributable to an increase in the charge carrier recombination rate, which counteracts the increased activity arising from the higher specific surface area for a sufficiently small particle size.

Designing a low cost solar collector system for process industry applications

New Zealand is a large producer and processor of primary products and has a climate with high levels of solar radiation. However, the use of solar energy for heating and cooling in the processing industries has received limited attention.
For this study, the design of a low cost solar collector is analysed and discussed. Furthermore, the methods for integrating the collector into water heating and cooling systems in a hypothetical processing environment are examined. An F-Chart analysis is used to simulate the performance of large-area arrays of the solar collector and to determine its potential contribution to heating and cooling loads.
The study shows that for a storage-based system, the contribution of solar energy is determined mainly by the collector area to storage volume ratio. It is suggested that this low cost collector could make a significant contribution to energy use in processing plants and may be an attractive future technology.

Solar industrial process heating in Australia - Past and current status

Thirty years ago in Australia, there was a significant research, development and demonstration programme in solar industrial process heating (SIPH). This activity was led principally by the Commonwealth Science and Industrial Research Organisation, the country’s main scientific research body. Other state government bodies also funded demonstration projects. Today, there is very little SIPH activity at any level in Australia. The contrast with the progress in other renewable energy technologies like wind and solar photovoltaic systems is striking. While the implementation of these technologies has progressed, SIPH has gone backwards. If Australia is to decarbonise its economy at the rate required, a massive deployment of solar thermal technology in those industries which use large quantities of low temperature hot water is also required. Recent developments nationally and internationally may rekindle new applications of solar thermal energy use by industry. This paper reviews the past achievements in SIPH in Australia and describes the lessons learned in order to better prepare for any new wave of SIPH activity.

Hydrogen bonding induced vesicular morphologies in diblock copolymer complexes

It is well-known that the self-assembly of block copolymers either in water or in organic solvents can form a wide range of morphologies in nanometer dimensions depending on its chemical nature. In the present study, the complexation and aggregate morphologies in a model AB/AC diblock copolymer system consisting of polystyrene-block-poly(acrylic acid) (PS-b-PAA) and polystyrene-block-poly(ethylene oxide) (PS-b-PEO) in water were studied using transmission electron microscopy (TEM), small angle X-ray scattering (SAXS), and dynamic light scattering (DLS). By varying the relative amounts of the two block copolymers, a variety of bilayer aggregates were formed, including vesicles, multilamellar vesicles (MLVs), thick-walled vesicles (TWVs), interconnected compound vesicles (ICCVs), and irregular aggregates. The hydrophobic PS blocks were segregated as the cores while the hydrogen bonded PEO and PAA blocks formed the coronae of bilayer aggregates. We also investigate how the addition of PS-b-PEO into PS-b-PAA solutions influences the aggregate morphology of the resulting complexes. This work introduces a viable route to multicompartment vesicles in aqueous solutions. The formation of block copolymer vesicles in water is of particular interest because of their potential in various applications.

Photocatalytic degradation of phenanthrene on soil surfaces in the presence of nanometer anatase TiO2 under UV-light

The effect of nanometer anatase TiO2 was investigated on the photocatalytic degradation of phenanthrene on soil surfaces under a variety of conditions. After being spiked with phenanthrene, soil samples loaded with different amounts of TiO2 (0 wt.%, 1 wt.%, 2 wt.%, 3 wt.%, and 4 wt.%) were exposed to UV-light irradiation for 25 hr. The results indicated that the photocatalytic degradation of phenanthrene followed the pseudo first-order kinetics. TiO2 significantly accelerated the degradation of phenanthrene with the half-life reduced from 45.90 to 31.36 hr for TiO2 loading of 0 wt.% and 4 wt.%, respectively. In addition, the effects of H2O2, light intensity and humic acid on the degradation of phenanthrene were investigated. The degradation of phenanthrene increased with the concentration of H2O2, light intensity and the concentration of humic acids. It has been demonstrated that the photocatalytic method in the presence of nanometer anatase TiO2 was a very promising technology for the treatments of soil polluted with organic substances in the future.

The contribution of residential solar energy systems to the reduction of greenhouse gas emissions in the borough of Queenscliffe

The Borough of Queenscliffe has identified the importance of reducing its greenhouse gas emissions and aims to become a carbon zero municipality by 2020. For a house, suburb or town to become carbon neutral ideally it produces an equivalent amount of energy from renewable resources to that which it consumes. By increasing the number of solar systems, both photovoltaic (PV) and hot water, in the residential sector, greenhouse gas emissions will be reduced. The number of solar systems located in the Borough of Queenscliffe has been estimated and a database of these systems has been created, including the size and panel orientation. The energy generated by each solar system, in addition to the reductions in greenhouse gas emissions, has been calculated for an average year.

Hydrogen evolution by a metal-free electrocatalyst

Electrocatalytic reduction of water to molecular hydrogen via the hydrogen evolution reaction may provide a sustainable energy supply for the future, but its commercial application is hampered by the use of precious platinum catalysts. All alternatives to platinum thus far are based on nonprecious metals, and, to our knowledge, there is no report about a catalyst for electrocatalytic hydrogen evolution beyond metals. Here we couple graphitic-carbon nitride with nitrogen-doped graphene to produce a metal-free hybrid catalyst, which shows an unexpected hydrogen evolution reaction activity with comparable overpotential and Tafel slope to some of well-developed metallic catalysts. Experimental observations in combination with density functional theory calculations reveal that its unusual electrocatalytic properties originate from an intrinsic chemical and electronic coupling that synergistically promotes the proton adsorption and reduction kinetics.

Sub-lethal UV-C radiation induces callose, hydrogen peroxide and defence-related gene expression in Arabidopsis thaliana

Exposure of plants to UV-C irradiation induces gene expression and cellular responses that are commonly associated with wounding and pathogen defence, and in some cases can lead to increased resistance against pathogen infection. We examined, at a physiological, molecular and biochemical level, the effects of and responses to, sub-lethal UV-C exposure on Arabidopsis plants when irradiated with increasing dosages of UV-C radiation. Following UV-C exposure plants had reduced leaf areas over time, with the severity of reduction increasing with dosage. Severe morphological changes that included leaf glazing, bronzing and curling were found to occur in plants treated with the 1000 J·m(-2) dosage. Extensive damage to the mesophyll was observed, and cell death occurred in both a dosage- and time-dependent manner. Analysis of H2 O2 activity and the pathogen defence marker genes PR1 and PDF1.2 demonstrated induction of these defence-related responses at each UV-C dosage tested. Interestingly, in response to UV-C irradiation the production of callose (β-1,3-glucan) was identified at all dosages examined. Together, these results show plant responses to UV-C irradiation at much lower doses than have previously been reported, and that there is potential for the use of UV-C as an inducer of plant defence.

Mitigation strategies of hydrogen sulphide emission in sewer networks - A review

Hydrogen sulphide (H2S) gas emission in sewer networks is associated with several problems including the release of dangerous odour to the atmosphere and sewer pipe corrosion. The release of odour can endanger public health and corrode sewer pipe walls. Sewer corrosion has the potential to cost water utilities millions of dollars to maintain and rehabilitate the affected sewer pipes. Some chemical mitigation strategies to control hydrogen sulphide emission have been introduced. These include but are not limited to the injection of oxygen, magnesium and sodium hydroxide, calcium nitrate and iron salts. The optimisation of the dosing rate and location of each chemical mitigation strategy is required to achieve maximum hydrogen sulphide gas removal efficiency along with cost effectiveness. In this review paper, the five most popular chemical mitigation strategies that were previously mentioned have been investigated and discussed. The article is broken down into three main discussions. Firstly the sewer transformation processes and factors affecting the hydrogen sulphide generation and emission are highlighted. Secondly, comparisons and differences between each selected chemical mitigation strategy as well as its application covered. Finally, the review of the chemical efficiency and cost is conducted by comparing two case studies in controlling the formation of dissolved sulphide. It was found that the injection of oxygen is the cheapest mitigation strategy of hydrogen sulphide gas generation in sewers, but least effective.