Runoff absorption potential of roofing materials

The main objectives of this work are to establish a relationship between solar radiation and equivalent temperatures for the radiation heat source (oven) to be used in the laboratory and to determine the impact of solar radiation on the absorption and evaporation potential of roofing tiles (glazed and unglazed). Based on the results obtained, it is justifiable to conclude that solar radiation do affect the evaporation and absorption potential of the glazed and unglazed tiles. There is a trend of decrease in both the absorption and evaporation potential of both tiles when exposed to decreasing solar radiation. The evaporation potential of the roof tiles is much higher than its absorption potential. This is clearly displayed in both types of tiles.

Novel polymer-ceramic composites for protection against ballistic fragments

For the first time, internally reinforced aggregate polymer ceramic composites were evaluated against fragment simulating projectiles (FSPs) of various calibers to investigate their ballistic impact response. Samples were prepared by mechanically mixing B4C and cBN over a range of ratios and combinations with either thermosetting phenolic or epoxy resin and aramid pulp. Dry mixtures were then molded in a closed die using a heated platen press. The resulting tiles were then mounted as ‘‘strike faces’’ to an aramid backing material using an epoxy resin. Backed targets were tested in a fully instrumented firing range against 5.56 mm FSPs to test ballistic limit. A further series of tests using 7.62, 12.5, and 20 mm FSPs was conducted to examine round deformation across a range of fragments calibers. Round deformations were measured after impact and plotted against shot velocity. It was found that the polymer ceramic composite materials were effective round deformers and, like sintered ceramic strike faces, demonstrated improved ballistic performance at an equivalent areal density and impressive multihit capability.

Application of very-high-frequency (VHF) method to ceramic insulators

A VHF method (30-300 MHz) is applied to identify faults and defects in ceramic insulators. Insulators which exhibit internal cracks and fractures are used as test samples. Different artificial conditions are introduced to the test samples according to the IEC 507 standard under wet and dry conditions. Using a cascading signal processing technique and analysis methods such as FFT and fractal analysis, VHF signals acquired by digital scope are processed and analyzed. This study indicates that the fractal dimension can be used as an effective tool to isolate the common faulty conditions found on the ceramic insulators. The results from this study strongly support the prospect of using a VHF method to monitor the physical condition of ceramic insulators.

Mechanical properties and energy absorption of ceramic particulate and resin-impregnation reinforced aluminium foams

The mechanical properties of aluminium foams can be improved by matrix reinforcement and resin-impregnation methods. In the present study, aluminium foams were reinforced by both ceramic particulate reinforcing of the aluminium matrix and resin-impregnating pores. The mechanical properties and the energy absorption of the reinforced aluminium foams were investigated by dynamic and quasi-static compression. Results indicated that the ceramic particle additions of CBN, SiC and B4C in aluminium foams increase the peak stress, elastic modulus and energy absorption of the aluminium foams, under both conditions of dynamic and quasi-static compression. Moreover, the aluminium foams with and without ceramic particle additions exhibited obvious strain rate sensitivity during dynamic compression. Furthermore, the resin-impregnation improves the mechanic properties and energy absorption of aluminium foams significantly. However, aluminium foams with resin-impregnation showed negligible strain rate sensitivity under dynamic compression. It is reported that both the ceramic particle addition and resin-impregnation can be effective techniques to improve the mechanical and the energy absorption properties of aluminium foams.

UV-shielding ceramic nanoparticles synthesised by mechanochemcial processing

ZnO, TiO₂ and CeO₂ are known as UV-shielding ceramic materials that have advantages over organic UV absorbers for their photo-stability and non-hazardous nature to human bodies. However, they normally cause low transparency in the visible-light range due to light scattering by large particles, which is undesirable for many transparent UV-blocking applications in cosmetic and plastic industries. Light-scattering efficiency of particles can be drastically reduced by decreasing the particle sizes down below 100 nm. This paper reviews recent investigation on the synthesis of ZnO and CeO₂ nanoparticles by mechanochemical processing. The resulting particles had a significantly low degree of agglomeration, having mean particle sizes of ~ 25 nm and ~ 10 nm, respectively. The aqueous suspensions of the nanoparticles showed strong absorption in the UV-light range and high transmittance in the visible-light range. Mechanochemical processing offers the possibility of industrial-scale production of transparent UV-shielding ceramic particles for many applications.

Green roof retrofit potential in the central business district

Purpose – The purpose of this paper is to illustrate the potential for green roof retrofit to commercial buildings in a city centre to property managers and other property professionals.

Design/methodology/approach – This paper addresses the research question: what is the potential of existing buildings in the CBD to accommodate a retrofitted green roof? Furthermore, it questions how many buildings are suitable for green roofs? The researchers compile a unique building database incorporating information about 536 commercial buidings and evaluate the potential suitability of each building to undergo a green roof retrofit. Assisted by other commercially available databases and software, the researchers are able to assess each roof based on criteria derived from an extensive literature review.

Findings – A relatively small proportion of roofs are found to be suitable, partly a result of local climate conditions and rainfall patterns, and the physical property stock. On a purely physical assessment, only a very small proportion of CBD stock is found to be suited. These buildings are most likely to be in low secondary locations, ungraded or B grade buildings, privately owned, concrete framed and not overshadowed by adjoining properties.

Practical implications – Property managers and other property professionals can now determine the potential of their portfolio stock for green roof retrofit based on the review of building attributes required for success adaptation in this paper. It possible that greater potential for green roof retrofit exists in the suburbs or regional towns where lower rise buildings may reduce the amount of overshadowing found in city centres. Follow-up research could focus on a comparison of regional and suburban developments.

Originality/value – This is the first study of its kind and has assessed such a large number of buildings for their suitability for green roof retrofit; the findings provide a reliable guide for policymakers regarding the potential number of city centre buildings which would be possible to retrofit. Such findings should influence policymaking and incentives to target effective sustainability policies with regards to existing buildings.

The Sawankhalok ceramic industry

A techno-historical study of a commercial initiative by 13th century Thai village potters to produce domestic stoneware ceramics. However their enterprise's success attracted the exploitative interest of regional trade entrepreneurs whose specialisation of the industry created a fatal lack of efficiency and flexibility.

The enhancement of lithium ion dissociation in polyelectrolyte gels on the addition of ceramic nano-fillers

Nano-particle oxide fillers including TiO₂, SiO₂ and Al₂O₃ have previously been shown to have a significant affect on the properties of both polymer and polymer gel electrolytes. In some cases, conductivity increases of one order of magnitude have been reported in crystalline PEO–base complexes. In this work, we report the effects of TiO₂ and SiO₂ on a poly(Li-AMPS)-based gel polyelectrolyte. Impedance spectroscopy and pfg-NMR spectroscopy indicates an increase in the number of available charge carriers with the addition of filler. An ideal amount of ceramic filler has been identified, with additional filler only saturating the system and reducing the conductivity below that of the pristine polyelectrolyte system. SEM micrographs suggest a model whereby the filler interacts readily with the sulfonate group; the surface area of the filler being an important factor.

Lithium-ion conducting ceramic/polyether composites

Composites of a lithium ion conducting ceramic with a lithium salt based polymer electrolyte matrix are described. Conductivity measurements as a function of the lithium ion conducting ceramic phase content in the composite show that there is a significant increase in conductivity at approximately 40 vol% of the ceramic. The room temperature conductivity above this ceramic content is enhanced by at least 100% over that of the polymer electrolyte phase alone. It is believed that this additional contribution is substantially lithium ion conduction. The major barrier to ion-motion in these materials appears to be the interface between the polymer and ceramic. This interfacial resistance is strongly moisture-sensitive.

Polymer-ceramic ion-conducting composites

Composites of a Li⁺ ion-conducting ceramic powder in a polyether-based elastomeric electrolyte matrix are described. At 66 wt.% of ceramic the composite can be prepared as a paste and cured into a coherent material having useful elastic and tensile properties. The total conductivity of the composite was found to be (1.9 ± 0.2) × 10⁻⁴ S cm⁻¹ at 40 °C which was approximately 1 order of magnitude higher than the polymer electrolyte component alone. The result was also approximately 1 order of magnitude higher than the total conductivity of the ceramic powders tested in this work.

Ceramic-polymer interface in composite electrolytes of lithium aluminium titanium phosphate and polyetherurethane polymer electrolyte

Composite electrolytes of the lithium-ion-conducting ceramic Li_1.3Al_0.3Ti_1.7(PO₄)₃ and polyetherurethane/lithium triflate polymer electrolyte have been prepared. Microscopy has shown that adhesion between the ceramic and polymer phases is poor, with gaps up to 1 μm at the interface. When dry, the composites are no more conductive than the pure polymer electrolyte. Exposing the samples to the vapour of solvents such as DMF, acetonitrile or water produces a significant increase in conductivity, over and beyond simple plasticization of the polymer. Pretreating the ceramic with a compatibilizing agent improves adhesion at the interface with the polymer, but decreases overall conductivity in the case investigated.