Microorganisms linked to Neoproterozoic microspar carbonate sedimentation in the Jilin-Liaoning area

Molar-tooth carbonate refers to a sort of rock that has ptygmatical folded structure comparable to the ivory. This kind of carbonate exists in a special time range (from Middle to Neoproterozoic). Its origin and the possibility to use it in stratigraphic correlation of the paleocontinent is the key task of the IGCP447, a project on Proterozoic molar tooth carbonates and the evolution of the earth (2001-2005). The importance lies in that the molar-tooth structure is the key to solving problems related to Precambrian biological and global geochemical events. The molar-tooth structure is associated with microorganisms. Development and recession of such carbonates have relations with the evolution process of early lives and abrupt changes in sea carbonate geochemistry. In recent years, based on researches on petrology, geochemistry and Sr isotope of molar-tooth carbonate in the Jilin-Liaoning and Xuzhou-Huaiyang area, the authors hold that it can be used as a marker for stratigraphic sequence and sedimentary facies analyses.

Microorganisms linked to Neoproterozoic microspar carbonate sedimentation in the Jilin-Liaoning area

Molar-tooth carbonate refers to a sort of rock that has ptygmatical folded structure comparable to the ivory. This kind of carbonate exists in a special time range (from Middle to Neoproterozoic). Its origin and the possibility to use it in stratigraphic correlation of the paleocontinent is the key task of the IGCP447, a project on Proterozoic molar tooth carbonates and the evolution of the earth (2001-2005). The importance lies in that the molar-tooth structure is the key to solving problems related to Precambrian biological and global geochemical events. The molar-tooth structure is associated with microorganisms. Development and recession of such carbonates have relations with the evolution process of early lives and abrupt changes in sea carbonate geochemistry. In recent years, based on researches on petrology, geochemistry and Sr isotope of molar-tooth carbonate in the Jilin-Liaoning and Xuzhou-Huaiyang area, the authors hold that it can be used as a marker for stratigraphic sequence and sedimentary facies analyses.

Measures for describing the size distribution of sediments

Numerous measures are used in the literature to describe the grain-size distribution of sediments. Consideration of these measures indicates that parameters computed from quartiles may not be as significant as those based on more rigorous statistical concepts. In addition, the lack of standardization of descriptive measures has resulted in limited application of the findings from one locality to another. The use of five parameters that serve as approximate graphic analogies to the moment measures commonly employed in statistics is recommended. The parameters are computed from five percentile diameters obtained from the cumulative size-frequency curve of a sediment. They include the mean (or median) diameter, standard deviation, kurtosis, and two measures of skewness, the second measure being sensitive to skew properties of the "tails" of the sediment distribution. If the five descriptive measures are listed for a sediment, it is possible to compute the five percentile diameters on which they are based (phi 5 , phi 16 , phi 50 , phi 84 , and phi 95 ), and hence five significant points on the cumulative carve of the sediment. This increases the value of the data listed for a sediment in a report, and in many cases eliminates the necessity of including the complete mechanical analysis of the sediment. The degree of correlation of the graphic parameters to the corresponding moment measures decreases as the distribution becomes more skew. However, for a fairly wide range of distributions, the first three moment measures can be ascertained from the graphic parameters with about the same degree of accuracy as is obtained by computing rough moment measures.

Metasomatism of the peridotites from southern Mariana fore-arc: Trace element characteristics of clinopyroxene and amphibole

Modal composition and mineral composition of harzburgites from the southern Mariana fore-arc show that they are highly refractory. There are a few modals of clinopyroxene (0.7 vol %) in harzburgites. Two types of amphibole are found in these harzburgites: magnesiohornblende accompanied by clinopyroxene with higher Al2O3 content (> 7%) and lower Mg-#; tremolite around orthopyroxene with lower Al2O3 content (< 2%) and higher Mg-#. Trace element of clinopyroxene and two types of amphibole are analyzed. Primitive mantle-normalised REE patterns for clinopyroxene and magnesio hornblende are very similar and both show HREE enrichment relative to LREE, while magnesiohornblende has higher content of trace element than clinopyroxene. The contents of trace element of tremolite are much lower than those of magnesiohornblende. Clinopyroxene shows enrichment of most of the trace element except HREE and Ti relative to clinopyroxene in abyssal peridotites. Petrology and trace element characteristic of clinopyroxene and two types of amphibole indicate that southern Mariana fore-arc harzburgites underwent two stages of metasomatism. The percolation of a hydrous melt led to mobility of Al, Ca, Fe, Mg, Na, and large amounts of trace element. LILE and LREE can be more active in hydrous melt than HREE and Ti, and the activities of most of the trace element except some of LILE are influenced by temperature and pressure.

大陆地壳岩石结构重建：方法与实例

The composition of the continental crust has long been a subject of interest to earth scientists as it can provide key information about the crustal growth and evolution of the continents. In this paper we make a comparative study on the lithological discrimination schemes featuring with the use of different seismic attributes, such as P-wave velocity, P- to S-wave velocity ratio, acoustic or elastic impedances, Lame impedances and high-sensitive identification factors. The results demonstrate that Lame impedances have more powerful constrains than other seismic attributes. In order to fully take the advantage of make the best of the different seismic response of crustal rock, we firstly use seismic attribute that have weak distinguish power to construct loose constrained lithological model, then use seismic attributes that have stronger distinguish power to tighten the constrains of lithological discrimination. We propose a joint scheme (chain constrain technique) by combing all available constrains to reduce the non-uniqueness in mapping rock distribution. We adopt chain constrain technique to construct lithological model beneath Tunxi-Wenzhou transect, Southeastern China, Manzhouli-Suifenhe transect, Northeastern China, and geophysical profile in Bohai Bay Basin, North China. The results can be suumarized as the follows: (1) We compare the sensitivity of different seismic factor constraints on rock types, and conclude that Lame impedances have tighter constrains than seismic velocity, Vp/Vs, density. (2) We propose chain constrains to construct lithological model from integrated geophysical data, and reduce the non-uniqueness in mapping rock distribution. (3) We reconstruct crustal lithological model beneath Tunxi-Wenzhou transect, Southeastern China. The results suggested that Jiangshan-Shaoxing fault is a crust-scale, and it is the boundary between Cathaysia and Yanthze blocks. (4) We construct crustal lithological model beneath Manzhouli-Suifenhe transect, Northeastern China. (5) We map the petrologic distribution along a geophysical profile in Bohai Bay Basin, North China, and construct a three-layered petrology model from the depth 2 km to about 10 km, consisted of basalt (the first layer), pelitic siltstone (the second layer), and silty mudstone and fine sandstone (the third layer).

油气、微生物与砂岩型铀矿形成关系研究——以东胜铀矿床和钱家店铀矿床为例

Sandstone-type uranium deposits are frequently found close to oil fields or uraniferous sandstones contain bitumen or petroleum. However, few evidence has been presented to indicate the association of uranium mineralization with petroleum oxidation. Thus, Dongsheng uranium deposit in Ordos Basin and Qianjiadian deposit in Kailu Basin are taken for examples to solve the puzzle. Integration data from sedimentary petrology, mineralogy, race elements geochemistry, isotope geochemistry and organic geochemistry, the uranium and petroleum sources, and diagenetic paragenesis of the host sandstone are analyzed, and then the genetic relationship between microbes, petroleum and uranium deposits are discussed. The observation under microscope shows that the host sandstone samples from Middle Jurassic Zhiluo Formation in the Dongsheng deposit contained different kinds of metamorphic rock fragments, which should have been derived form outcrops north to this basin. The LREE/HREE ratios of gneiss and amphibolite sampled from outcrops were close to the highest and the lowest LREE/HREE ratios of the sandstones with well-compared chondrite-normalized REE patterns, respectively. So these results consistently indicated that parent rocks of sandstones were mainly contributed from these two kinds of metamorphic rocks. There was very high Th/U ratio for granite gneiss, which was a mainly potential U resource. Hydrocarbon inclusions and adsorbed hydrocarbons are observed under fluorescence microscope in the host sandstone of Dongsheng uranium deposit, suggesting that the sandstones may have been utilized as oil migration pathways. Based on biomarker parameters, it is indicated that the inclusion oils and adsorbed hydrocarbons were marginally mature to mature, and were derived from humic-sapropel type organic matter under poor reducing freshwater to semi-saline environment. The features are similar to those of organic matter extracted from Triassic sandstone and source rock, but are different from that of cretaceous sandstone. Thus, it can be concluded that the inclusion oils and adsorbed hydrocarbons were mainly derived from Triassic lacustrine facies source rock. Observation results under Scanning Electron Microscopy and Electron Microprobe with Energy Spectrum Analysis show that, in Dongsheng area, the main uranium ore mineral is coffinite. The coffinite is intimately intergrown or coexists with pyrite and calcite, thus, the solution during mineralization stage is inferred to be alkaline. The alkaline environment is not favored for uranium to be pre-concentrated by absorption, and then be reduced abiogenetically. δ34S of pyrite and δ13C of calcite indicate that pyrite was formed by bacterial sulfate reduction (BSR) and part of the carbon of calcite has been dirived from oxidation of petroleum, respectively. Additionally, petroleum is found biodegraded. All the lines of evidence consistently indicate that petroleum was involved in uranium mineralization. Coffinite with microbe-like structures is found in the high U sandstone samples and is composed of nanoparticles, indicating the coffinite is biogenic. The conclusion are also supportted by laboratory experiment studies, which have shown that SRB are capable of utilizing U(VI) as the preferred electron acceptor for respiration and reduce U(VI) to U(IV) directly, coupled the oxidaton of organic matter and sulfate reduction. Based on the research results mentioned above, in the Dongsheng area, coffinite is likely to have formed by mixing of brine containing petroleum derived from Triassic with uranium-bearing meteoric water from outcrops north to Ordos Basin. SRB utilize hydrocarbon as carbon source, and directly reduce U(VI) resulting in precipitation of coffinite. The product of metabolism, H2S and CO2, was precipitated as pyrite and calcite during mineralization stage. Petroleum in fluid inclusions and adsorbed type in host sandstone from Lower Cretaceous Yaojia Formation in Qianjiadian uranium deposit, Kailu Basin, are derived from Jurassic Jiufotang Formation in this basin and the uranium mineral consists mainly of pitchblende. The δ34S and δ13C values of pyrite and calcite during mineralization stage indicate SRB have likely degraded petroleum, which is similar to that of Dongsheng deposit. The alkaline environment as indicated by the diagenetic mineral assemblage calcite, Fe dolomite, pyrite and pitchblende deposit suggests that U ore in the Qiangjiajiadian has a similar origin, i.e., direct reduction by SRB. However, less part of pitchblende is intergrown with kaolinite, suggesting the solution during mineralization stage is acidic. The environment is favorable for U(VI) to be adsorded on quartz or other mineral, and then reduced by H2S produced by SRB. Thus, it can be concluded that U(VI) reduction with petroleum oxidation by SRB and other microbes is an important ore-forming mechanism in petroleum-related sandstone-type uranium deposits. The finding is significant in that it provides a theoretical basis for exploration of both uranium and petroleumr.

大兴安岭北段晚中生代火山岩地球化学特征及其地质意义

This thesis mainly concentrates on the geochronology, prtrology, elemental geochemistry and Sr-Nd-Pb-Hf isotopic geochemistry of the volcanic rocks in north Da’Hinggan Mountain. By analyzing the data obtained in this study and data from other people, this thesis explored the age distribution, petrology and mineralogy and geochemistry characteristics of the volcanic rocks in north Da’Hinggan Mountain. Furthermore, this thesis speculated upon the source characteristics of these volcanic rocks and their implications for the tectonic evolution and crust accretion. According to the twenty Ar-Ar ages, four zircon U-Pb SHRIMP ages and two Zircon U-Pb LA-ICP-MS ages, the duration of the eruption of the Late Mesozoic volcanic rocks in north Da’Hing Mountain was about 160Ma-106Ma. Most of these volcanic rocks belong to early Cretaceous and the late Jurassic volcanic rocks are only restricted in Manzhouli. The bulk of the late Mesozoic volcanic rocks are high-K calc-alkaline rocks. Only a small portion of these volcanic rocks are shoshonites. These rocks are mainly intermediate or acid and the basic rocks usually have higher alkaline contents. Rock types are very complex in this region. These volcanic rocks have a large TiO2 variation and the Al2O3 and alkaline contents are high. From the point of mineralogy, the plagioclases in these volcanic rocks are oligoclases, andesines and labradorites, and the labradorites are more common. Most pyroxenes in these volcanic rocks are augites which belong to clinopyroxene. The source of the Late Mesozoic volcanic rocks was an enriched lithospheric mantle. When the magma en route to the surface it was contaminated by crust material slightly and had some fractional crystallization. These rocks which mainly belong to high-K calc-alkaline series were one of the results of postorogenic tectonic-magmatic activities. The upwelling in late Mesozoic supplied heat to melt the enriched lithospheric mantle which was resulted from the subduction of paleo-Asian Ocean and/or Mengol-Okhotsk ocean. These late Mesozoic volcanic rocks are also important to the upper crustal accretion of north Da’Hinggan Mountain since the late Mesozoic. These volcanics and the contemporary emplacement of granites and the basaltic underplating in combination fulfilled the crust accretion history in north Da’Hinggan Mountain in Late Mesozoic.

辽河盆地西部凹陷深部流体的地球化学特征与成藏效应

The main research area of this thesis is the Western Depression in the Liaohe Basin. Based on the drilling core observation and mud logging data, the features of the mantle–derived fluids and their effects on oil/gas generation in the Western Depression of the Liaohe Basin,was studied with comprehensive methods of volcanic petrology, sediment petrology, fluid geochemistry, sedimentlogy, and structural geology, and use of polarized light microscope, fluorescence microscope, electron microscope, fluid and melt inclusion test, and isotopic test of nature gas etc. The observation of drill cores in study area and other studies reveal that the main passageway of the volcanic eruption in the Cenozoic was the Xibaqian-Gaosheng fault, and the volcanic rocks of each stage were distributed around it. Mantle-derived fluid which affected on oil/gas generation formed later than the volcanic spew and those fluids entered into the depression through the Taian-Dawa fault and the Central fault. The volatile fraction analysis of the melt inclusion reveals the presence of two kinds of mantle fluids; they are hydrogen-rich fluid and carbon dioxide-rich fluid. These the two kinds of fluids were mainly distributed in olivine and pyroxene respectively. The hydrothermal veins development have multiple stages, from high temperature quartz vein to low temperature calcite vein and analcime vein, in which the fluid inclusion extremity component are methane and carbon dioxide, which indicate that when mantle-derived fluids ascended and entered into the basin, most of these fluids interacted with the organic matter in the basin even though some of these entered into atmosphere. The present isotopic test of the nature gas reveals the high 3He/4He value between the region of the Taian-Dawa fault and the Central fault, which also imply the feature of origin in mantle. This phenomenon indicates that the Mesozoic basement faults and the main Cenozoic faults had connected crust and the mantle during the basin evolution, so the mantle derived fluids could enter the basin along those faults. The main source rocks of the ES3 and ES4 members of the Shahejie Formation began to expel hydrocarbon at the end period of the ES1 member of the Shahejie Formation, and reached its peak during the period of the Dongying Formation deposition. During these periods, the mantle derived-fluids entered the basin constantly along the main faults, and supplied lots of hydrogen for hydrocarbon generation. Though the volcanic rocks and the mantle-derived fluids in the Eastern Depression were more developed than in the Western Depression, the source rocks and the deep fluids were not interacted better than the Western Depression because of the affection of structural evolution. In the Eocene, the Eastern Depression did not deposit the ES4 member of the Shahejie Formation, furthermore, the mantle-fluid formed in the Fangshengpao stage escaped to the atmosphere, which confined the later stage hydrocarbon generation capability.

西秦岭新生代火山岩中的地幔捕虏体和捕虏晶研究

Western Qinling, a conjunction region of the North China Craton, the Yangtze Craton and the Tibetan Plateau, has very complicated history of geologic and tectonic evolution. Previous studies mainly focus on tectonics and petrology of volcanic rocks in the western Qinling. Therefore, little is known about the Cenozoic lithospheric mantle beneath the western Qinling. Mafic, ultramafic and/or alkaline volcanic rocks and their entrained mantle peridotitic xenoliths and xenocrysts are known as samples directly from the lithospheric mantle. Their petrological and geochemical characteristics can reflect the nature and deep processes of the lithospheric mantle. Cenozoic volcanic rocks in the western Qinling contain abundant mantle xenoliths and xenocrysts, which provide us an opportunity to probe the lithospheric mantle beneath this region and a new dimension to insight into geologic evolution. Cenozoic volcanic rocks (7-23 Ma) from the western Qinling are sparsely distributed in the Lixian-Dangchang-Xihe Counties, Gansu Province, China. Volcanic rocks contain plenty of mantle-derived xenoliths, including spinel lherzolites with subordinate wehrlite, dunite, olivine websterite, clinopyroxenite and garnet lherzolite, and few olivine, clinopyroxene and spinel xenocrysts. These peridotitic xenoliths show clear deformed textures and their major minerals show excellent orientation. Thus, these peridotites are typical deformed peridotites. Olivine xenocrysts have clearly-zoned textures. The peridotitic xenoliths can be divided into two groups based on their compositions, namely, the H-type and L-type. The H-type peridotites are characterized by high Fo (>90) in olivines in which fine-grained ones have higher Fo than the coarse grains, low CaO (<20 %) in clinopyroxenes, high Cr# (>40) in spinels and high equilibration temperatures. They may represent the refractory lithospheric mantle. In contrast, the L-type peridotites contain low Fo (<90) olivines (with lower Fo in fine-grained olivines), high CaO (>20 %) clinopyroxenes, low Cr# (<20) spinels and low equilibration temperatures. They experienced low degree of partial melting. The Cenozoic lithospheric mantle beneath the western Qinling was refractory in major element compositions based on the mineral compositions of xenoliths and xenocrysts and experienced complicated deep processes. The lithospheric mantle was modified by shear deformation due to the diapirism of asthenosphere and strong tectonic movements including the collision between North China Craton and Yangze Craton and the uplift of Tibetan Plateau, and then underwent metasomatism with a hydrous, Na, Ti and Cr enriched melt.

陕北地区石家湾-李家岔探区三叠系延长组石油成藏条件分析

Shijiawan –Lijiacha area, lying on the northeastern part of the Shanbei Slope of Ordos Basin, was selected as studying area. The previous explorations proved that the 2nd segment and 6th segment of the Yanchang Formation are the most important oil-bearing formations. It is indicated that the sedimentary facies and reservoir characteristics restricted the hydrocarbon accumulation regularity. Therefore, with petrology methodologies, such as outcrop observation, core description, geophysical logging interpretation, thin section determination, scanning electron microscope, as well as rock property analysis, the reservoirs was were systematically studied and characterized. The sedimentary micro-facies, seals, reservoir-seal combines, migration pathways and entrapping modes were taken into account. The author tempted to establish a base for further studies on reservoirs and on petroleum geology, and to provide some reliably geological evidences for later prospect activities. It was found that the sediments in the 2nd and 3rd segments of the Yanchang Formation in Shijiawan –Lijiacha area were deposited in braided rivers, and most sandy-bodies were identified as channel sandbars. The 4+5th and 6th segments were principally deposited in deltaic-plain environment, consisting of corresponding sub-facies such as distributary channels, natural levee, crevasse-splay and marsh. The skeleton sandy-bodies were identified as sandy sediments of distributary channels. The sand grains in reservoir in studied area possess generally low mineralogical maturity and moderate structural maturity, and the form of pores may be classified into intergranular types and dissolved types. Most reservoirs of Yanchang Formation in Shijiawan –Lijiacha area belong to extreme low-porosity low-permeability ones (type III), and the 2nd sediments belongs to low permeability one (type II) and the 6th segment belong to super low-permeability one(type Ⅳ). The reservoirs in the 2nd segment behave more heterogeneous than those in the 6th segment. The statistic analysis results show that, for 6th and 4+5th segments, the high quality reservoir-seal combines may be found everywhere in the studied area except in the northwest and the southwest parts; and for 1st and 2nd segments, in the northeast, central and southwest parts Petroleum migration happened in the duration of the Early Cretaceous period in both lateral and vertical directions. The migration paths were mainly constructed by permeable sandy-bodies. The superimposed channel sandy-bodies consist of the principal part of the system of carriers. the vertical fractures, that may travel through the seals between reservoirs, offered the vertical paths for migrating oil. It may be synthesized that oil coming from south kitchens migrated first laterally in carriers in the 6th segment. When arrived at the studied area, oil will migration laterally or/and vertical within both the sandy-bodies and fractures, in a climbing-stair way. The results demonstrate that the oil was entrapped in traps structure-lithology and/or lithology traps. In some cases, the hydrodynamic force may help to trap oil. Accumulation of oil in the area was mainly controlled by sedimentary facies, seals, structure, and heterogeneity of reservoir in the 2nd, 4+5th and 6th segments. Especially, the oil distributions in both the 2nd and 6th segments were obviously influenced by seals in the 4+5th segment. The existence of seals in 1st segment seems important for accumulation in the 2nd segment.

束鹿凹陷泥灰岩储层综合评价与加砂压裂技术研究与应用

Luo Ning ( Mineralogy, Petrology, Deposit Mineralogy) Directed by Fu Liyun With the increase of the level of exploration and development, North China field, as one of the maturing fields in the east, has gradually turned their prospecting targets to frontiers such as deep zones, lithologic hydrocarbon reservoirs, low permeable layers, special lithostromes, etc, which propose new challenges to mating technique of exploration engineering. In it, the special lithostrome of clay carbonate in Shu-Lu cave in Middle Flank exploration area locates in Es_3 generating rock. The area distribution is large, formation thickness is over 100 meters, the oil accumulation condition is excellent, prognostic reserves is over 80,000,000 tons, but how to effectively stimulate the special low permeable and fractured reservoir has become the bottle neck problem of stimulation and stable yields. In this thesis, through comprehensive evaluation and analysis of lithology, lithomechanics, hydrocarbon reservoir characteristics, the characteristics of fluid flow through porous medium and the stimulation measures in the past, we acquire new cognition of clay carbonate reservoirs, in addition, the research and application of first hydraulic fracturing has gained positive effect and formed commensurable comprehensive reservoir evaluation technique and mating engineering technique of hydraulic fracturing. The main cognitions and achievements are as follows: 1.Study of geological information such as lithololy analysis and nuclear magnetic logging, etc, indicates that clay carbonate formation of Shu-Lu cave is anisotropic, low permeable with high shale content, whose accumulation space gives priority to microcracks. 2.The analysis of lithomechanics of clay carbonate indicates that the hardness is moderate, Young’s modulus is between that of sandstone and limestone, clay carbonate presents plastic property and its breakdown pressure is high because of the deep buried depth. 3.The analysis of the drillstem test curves indicates that the flow and build-up pressure curve of clay carbonate of Shu-Lu cave mainly has three types: formation contamination block-up type, low permeable type, formation energy accumulation slowness type; the reservoir characteristics presents double porosity media, radial compounding, uniform flow vertical fracture, isotropy, moniliform reservoir type. The target well Jingu 3 belongs to moniliform reservoir type. 4.Through recognition and re-evaluation of the treatment effect and technologic limitations of acidizing, acid fracturing and gelled acidizing in the past, based on the sufficient survey and study of hydraulic fracturing home and abroad, combined with comprehensive formation study of target well, we launched the study of the optimization of hydraulic fracturing technique, forming the principal clue and commensurable mating technology aimed at clay carbonate formation, whose targets are preventing leak off, preventing sand bridge, preventing embedment, controlling fracture height, forming long fracture. 5. Recognition of stimulation effect evaluation.

化德群和土门群沉积岩碎屑锆石研究：对华北克拉通基底及元古宙盆地演化的指示意义

The Huade Group, consisting of low-grade and un-metamorphosed sedimentary rocks with no volcanic interlayer, is located at the northern margin of the North China craton and adjoining the south part of the Central Asian Orogenic Belt. It is east to the Paleo- to Meso-Proterozoic Bayan Obo and Zhaertai-Langshan rifts and northwest to the Paleo- to Neo-proterozoic Yanshan aulacogen, in which the typical Changcheng, Jixian and Qingbaikou systems are developed. The Huade Group are mainly composed of pebbly sandstones, sandstones, greywackes，shales，calc-silicate rocks and limestones, partly undergoing low-grade metamorphism and being changed to meta-sandstones, schists, phyllites, slates and crystalline limestones or marbles. The stratigraphic sequences show several cycles of deposition. Each of them developed coarse clastic rocks – interbedded fine clastic rocks and pelites from bottom upward or from coarse clastic rocks to interbedded fine clastic rocks and pelites to carbonate rocks. The Tumen Group outcrop sporadically around or west to the Tanlu faults in western Shandong. They are mainly composed of pebbly sandstones, sandstones, shales and limestones. This thesis deals with the characteristics of petrology, geochemistry and sedimentary of the Huade Group and the Tumen Group, and discusses the LA-ICP-MS and SIMS U-Pb ages, Hf isotope and trace element composition of the detrital zircons from 5 meta-sandstone samples of the Huade Group and 3 sandstone samples of the Tumen Group. The age populations of the detrital zircons from the Huade Group are mainly ~2.5 Ga and ~1.85 Ga, and there are also minor peaks at ~2.0 Ga, ~1.92 Ga and ~1.73 Ga. Most of the detrital zircon grains of 2.47-2.57 Ga and a few of 1.63-2.03 Ga have Hf crust model ages of 2.7-3.0 Ga, and most of the detrital zircon grains of 1.63-2.03 Ga have Hf crust model ages of 2.35-2.7 Ga, with a peak at 2.54 Ga. The main age peaks of the detrital zircons from the Tumen Group are ~2.5 Ga、~1.85 Ga, 1.57 Ga, 1.5 Ga, 1.33 Ga and 1.2 Ga. Different samples from the Tumen Group have distinct Hf isotopic characteristics. Detrital zircon grains of ~2.52 Ga from one sandstone sample have 2.7-3.2 Ga Hf crust model ages, whereas zircon grains of 1.73-2.02 Ga and 2.31-2.68 Ga from another sample have Hf crust model ages of 2.95-3.55 Ga. Detrital zircon grains of Mesoproterozoic ages have Paleoproterozoic (1.7-2.25 Ga) crust model ages. Through detailed analyses of the detrital zircons from the Huade and Tumen Group and comparison with those from the sedimentary rocks of similar sedimentary ages, the thesis mainly reaches the following conclusions: 1. The youngest age peaks of the detrital zircons of 1.73 Ga constrains the sedimentary time of the Huade Group from late Paleoproterozoic to Mesoproterozoic. 2. The age peaks of detrital zircons of the Huade Group correspond to the significant Precambrian tectonic-thermal events of the North China craton. The basement of the North China craton is the main provenance of the Huade Group, of which the intermediate to high grade metamorphic sedimentary rocks are dominant and provide mainly 1.85-1.92 Ga sediments. 3. The Huade basin belongs to the North China craton and it is suggested that the northern boundary of the North China craton should be north to the Huade basin. 4. The stratigraphic characteristics indicate the Huade Group formed in a stable shallow-hypabyssal sedimentary basin. The rock association and sedimentary time of the Huade Group are similar to those of the Banyan Obo Group and the Zhaertai Group, and they commonly constitute late Paleoproterozoic to Mesoproterozoic continental margin basins along the northern margin of the North China craton. 5. The continental margin basins would have initiated coeval with the Yanshan and Xiong’er aulacogens. 6. The ages of the detrital zircons from the Tumen Group and the Penglai Group at Shandong peninsula and the Yushulazi Group at south Liaoning are similar, so their sedimentary time is suggested to be Neoproterozoic，coeval with the Qingbaikou system. The detrital zircon ages of 1.0-1.2 Ga from the Tumen Group, the Penglai Group and the Yushulazi Group indicate that there have being 1.0-1.2 Ga magmatic activities at the eastern margin of the North China craton. 7. The U-Pb age populations of the detrital zircons from the late Paleoproterozoic to Neoproterozoic sedimentary rocks suggest that the main Precambrian tectonic-thermal events of the North China craton happened at ~2.5 Ga and ~1.85 Ga. But the events at 2.7 Ga and 1.2 Ga are also of great significance. Hf isotope characteristics indicate that the significant crust growth periods of the North China craton are 2.7-3.0 Ga and ~2.5 Ga.

内蒙古克什克腾旗小东沟斑岩型钼矿床的成矿作用

In this paper, the Xiaodonggou porphyry molybdenum deposit located in the Xarmoron molybdenum metallogenic belt is chose as the research area. We have analyzed the petrology of the Xiaodonggou pluton in detail and made chemical analysis of the major and trace elements, Rb-Sr and Sm-Nd isotope, common lead isotope and SHRIMP zircon U-Pb dating et al; in the other hand, we use the molybdenite to make common lead analysis and Re-Os isotopic dating. The Xiaodonggou pluton is rich in silicon, potass, zirconium, and low in REE. In addition, it has no minus Eu abnormity and show a isotopic composition high in εNd(t) and low in Sri, indicating its magma origining from the melting of juvenile thicken lower crust. In the meanwhile, it contained the features of high temperature, quick melting, quick segregation and quick emplacement. The common lead analysis of the pluton orthoclase and molybdenite show that the former transfer from orogen to mantle and the latter come from mantle, which is consistent to the molybdenite sulfur isotopic and quartz oxygen isotopic composition, demonstrating that the rock and ore-forming materials of deposit having different sources, magma from the lower crust mixing with mantle fluid. In plus, we use the physical experiments results of the water-magma reaction to explain the interaction of magma and mantle fluid. In the deep crust, these two systems uplifted in a immiscible state; when they reached low depth, the stream film between fluid-magma collapsed, and the magma was broken into small agglomerates by the fluid, then they mixed thoroughly. The SHRIMP zircon U-Pb dating gave a result of 142±2Ma and the molybdenite Re-Os dating result is 138.1±2.8Ma, corresponding to the big tectonic transition period of 140Ma, when the major stress field changing from south and north to west and east. At this time, the Da Hinggan ling ranges area was under an extensive background, underplating proceeded and mantle materials could add into the magmas forming in the lower crust. So, from the above analysis, we propose the following model for the Xiaodonggou porphyry molybdenum deposit: in the early Cretaceous period, the Da Hinggan ling ranges area was under a extensive background, the adding of mantle fluid containing ore materials into heated lower crust made it melting to produce magmas. Following more mantle fluid got into the magma room and urged the magma to segregate from the source quickly. The fluid and magma uplifted together, when they arrived at shallow depth, the fluid-magma became unstable and the latter was broken into many small agglomerates with fluid connecting them in the interspaces. Because of the H+, K+ and various elements existing in the fluid, it would reacted with the magma and the rock through alteration and ore minerals crystallized out, forming the Xiaodonggou porphyry deposit with disseminated mineralization phenomenon.