Catalytic Asymmetric Transfer Hydrogenation of Imines: Recent Advances


Autoria(s): Foubelo, Francisco; Yus, Miguel
Contribuinte(s)

Universidad de Alicante. Departamento de Química Orgánica

Universidad de Alicante. Instituto Universitario de Síntesis Orgánica

Síntesis Asimétrica (SINTAS)

Data(s)

22/09/2016

22/09/2016

01/10/2015

Resumo

In this review article recent developments in the asymmetric transfer hydrogenation of imines from 2008 up to today are presented. The main methodology involves either metal-catalyzed procedures in the presence of a chiral ligand or organocatalyzed technologies using a Hantzsch ester and a chiral BINOL-derived phosphoric acid. The most important procedures are collected, paying special attention to the application of this methodology in synthetic organic chemistry.

We thank the continued financial support from our Ministerio de Ciencia e Innovación (MICINN; projects CTQ2007-62771/BQU, CTQ2010-20387, CONSOLIDER INGENIO 2010-CDS2007-00006, CTQ2011-24151, CTQ2011-24165), the Ministerio de Economía y Competitividad (MINECO; projects CTQ2013-43446-P, CTQ2014-51912-REDC, CTQ2014-53695-P), FEDER, the Generalitat Valenciana (PROMETEO 2009/039, PROMETEOII/2014/017), and the University of Alicante.

Identificador

The Chemical Record. 2015, 15(5): 907-924. doi:10.1002/tcr.201500203

1527-8999 (Print)

1528-0691 (Online)

http://hdl.handle.net/10045/58134

10.1002/tcr.201500203

Idioma(s)

eng

Publicador

Chemical Society of Japan

Wiley-VCH Verlag GmbH & Co. KGaA

Relação

http://dx.doi.org/10.1002/tcr.201500203

Direitos

© 2015 The Chemical Society of Japan and Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

info:eu-repo/semantics/openAccess

Palavras-Chave #Asymmetric synthesis #Homogeneous catalysis #Hydrogen transfer, imines #Organocatalysis #Química Orgánica
Tipo

info:eu-repo/semantics/article