Degradation of compounds present in cork boiling water by gamma radiation


Autoria(s): Madureira, Joana; Barros, Lillian; Melo, R.; Santos, Pedro M.P.; Falcão, Antonio N.; Cabo-Verde, Sandra; Ferreira, Isabel C.F.R.; Margaça, Fernanda M.A.
Data(s)

16/09/2016

16/09/2016

2016

Resumo

Cork boiling water is an aqueous and complex dark liquor with high concentration of phenolic compounds such as phenolic acids and tannins [1, 2], which are considered biorecalcitrants [2]. Ionizing radiation has been widely studied as an alternative technology for the degradation of organic contaminants without the addition of any other (e.g.: Fenton technologies). The aim of this work was to identify the compounds present in cork boiling water and further evaluate the resulting stable degradation products after gamma irradiation. The irradiation experiments of standard solutions were carried out at room temperature using a Co-60 experimental equipment. The applied absorbed doses were 20 and 50 kGy at a dose rate of 1.5 kGy/h, determined by routine dosimeters [3]. The identification of radiolytic products was carried out by HPLC-DAD-ESI/MS. The phenolic compounds were identified by comparing their retention times and UV–vis and mass spectra with those obtained from standard compounds, when available, as well as by comparing the obtained information with available data reported in the literature. Concerning the obtained results and the literature review, the main cork wastewater components are: quinic, gallic, protocatechuic, vanillic, syringic and ellagic acids. Based on this, we used protocatechuic, vanillic and syringic acids as model compounds to study their degradation by gamma radiation in order to identify the corresponding radiolytic products. Standard aqueous solutions were irradiated and the derivatives of each model compound are represented in figure 1. The obtained results seem to demonstrate that the derivatives of the parent compounds could also be phenolic acids, since it was observed the loss of 44 u (CO2) from the [M-H]- ions. Gallic and protocatechuic acids are identified as derivatives of vanillic and syringic acids, and gallic acid as a protocatechuic acid derivative. Compound 5 ([M-H]- at m/z 169) was tentatively identified as 2,4,6-trihydroxybenzoic acid, since its fragmentation pattern (m/z 151, 125 and 107) is similar to that previously reported in literature [4]. The structure of compound 7 was proposed based on the molecular ion and its fragmentation and compound 6 remains unknown.

Identificador

Madureira, Joana; Barros, Lillian; Melo, R.; Santos, Pedro M.P.; Falcão, Antonio N.; Cabo-Verde, Sandra; Ferreira, Isabel C.F.R.; Margaça, Fernanda M.A. (2016) - Degradation of compounds present in cork boiling water by gamma radiation. In XVI Latin-American Congress on Chromatography & 9th National Metting on Chromatography. Lisboa

http://hdl.handle.net/10198/13245

Idioma(s)

eng

Relação

info:eu-repo/grantAgreement/FCT/3599-PPCDT/129707/PT

Direitos

openAccess

http://creativecommons.org/licenses/by/4.0/

Tipo

conferenceObject