Self-assembly of cyclometallated Pd(II) compounds directed by C-H center dot center dot center dot pi interactions: A structural evidence for metalloaromaticity in a cyclopalladated ring
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
01/01/2011
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Resumo |
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Structural studies on the two binuclear cyclometallated compounds [Pd(C-2,N-bzan)(mu-N-3)](2) (1) and [Pd(C-2,N-bzan)(mu-Pz)](2) (2) (bzan = N-benzylideneaniline) have been carried out in this work. In both compounds, C-H center dot center dot center dot pi interactions play an important role in the molecular self-assembly. In complex 1, ortho-CH bonds from bzan moiety interact with the cyclopalladated ring at a distance of C-bzan center dot center dot center dot C-g 3.448(6) angstrom, providing a new structural evidence for the metalloaromaticity of the cyclometallated ring. (C) 2010 Elsevier B.V. All rights reserved. |
Formato |
83-86 |
Identificador |
http://dx.doi.org/10.1016/j.inoche.2010.09.037 Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 14, n. 1, p. 83-86, 2011. 1387-7003 http://hdl.handle.net/11449/26021 10.1016/j.inoche.2010.09.037 WOS:000287269000021 |
Idioma(s) |
eng |
Publicador |
Elsevier B.V. |
Relação |
Inorganic Chemistry Communications |
Direitos |
closedAccess |
Palavras-Chave | #Supramolecular chemistry #C-H center dot center dot center dot pi interactions #Cyclopalladated #Metalloaromaticity |
Tipo |
info:eu-repo/semantics/article |