An electrochemical sensor for (L)-dopa based on oxovanadium-salen thin film electrode applied flow injection system
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
26/03/2007
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Resumo |
An oxovanadium-salen complex (NAP-ethylene-bis(salicylidenciminato) oxovanadium) thin film deposited on a graphite-polyurethane electrode was investigated with regard to its potential use for detection of L-dopa in flow injection system. The oxovanadium(IV)/oxovanadium(V) redox couple of the modified electrode was found to mediate the L-dopa oxidation before its use in the FIA system. Experimental parameters, such as pH of the carrier solution, flow rate, sample volume injection and probable interferents were investigated. Under the optimized FIA conditions, the amperometric signal was linearly dependent on the L-dopa concentration over the range 1.0 x 10(-1) to 1.0 x 10(-4) mol L-1 (I-anodic, mu A) = 0.01 + 0.25 [L-dopa mu mol L-1]) with a detection limit (S/N = 3) of 8.0 x 10(-7) mol L-1 and a sampling frequency of 90 h(-1) was achieved. For a concentration of 1.0 x 10(-5) mol L-1 L-dopa, the R.S.D. of nine consecutive measurements was 3.7%. (c) 2006 Elsevier B.V. All rights reserved. |
Formato |
549-555 |
Identificador |
http://dx.doi.org/10.1016/j.snb.2006.06.032 Sensors and Actuators B-chemical. Lausanne: Elsevier B.V. Sa, v. 122, n. 2, p. 549-555, 2007. 0925-4005 http://hdl.handle.net/11449/6824 10.1016/j.snb.2006.06.032 WOS:000245538300029 |
Idioma(s) |
eng |
Publicador |
Elsevier B.V. |
Relação |
Sensors and Actuators B: Chemical |
Direitos |
closedAccess |
Palavras-Chave | #modified electrode #oxovanadium-salen #amperometric detection (L)-dopa #flow analysis system |
Tipo |
info:eu-repo/semantics/article |