Concomitant reactivity of the m-Terphenylindium dihydroxide [2,6-Mes2C6H3In(OH)2]4 toward carbon dioxide and ethylene glycol
| Data(s) |
14/05/2012
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|---|---|
| Resumo |
The stepwise reaction of [2,6-Mes<sub>2</sub>C<sub>6</sub>H<sub>3</sub>In(OH)<sub>2</sub>]<sub>4</sub> with carbon dioxide and ethylene glycol proceeded with the formation of (2,6-Mes<sub>2</sub>C<sub>6</sub>H<sub>3</sub>In)<sub>4</sub>(CO<sub>3</sub>)<sub>2</sub>(OH)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub> (<b>1</b>) and (2,6-Mes<sub>2</sub>C<sub>6</sub>H<sub>3</sub>In)<sub>4</sub>(OCH<sub>2</sub>CH<sub>2</sub>O)<sub>2</sub>(OH)<sub>4</sub> (<b>2</b>), respectively, and eventually produced (2,6-Mes<sub>2</sub>C<sub>6</sub>H<sub>3</sub>In)<sub>4</sub>(CO<sub>3</sub>)<sub>2</sub>(OCH<sub>2</sub>CH<sub>2</sub>OH)<sub>2</sub>(OH)<sub>2</sub> (<b>3</b>). Attempts to liberate ethylene carbonate upon heating of 3 were unsuccessful.<br /> |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
American Chemical Society |
| Relação |
http://dro.deakin.edu.au/eserv/DU:30047045/duthie-concomitantreactivity-2012.pdf http://hdl.handle.net/10.1021/om3001857 |
| Direitos |
2012, American Chemical Society |
| Palavras-Chave | #ethylene carbonate #stepwise reaction |
| Tipo |
Journal Article |
