Ionic Recognition by 7-Nitro-1,3,5-triaza Adamantane: First Thermodynamic Study
Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
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Data(s) |
20/10/2012
20/10/2012
2009
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Resumo |
A thermodynamic study involving 7-nitro-1,3,5-triaza adamantane, 1, and its interaction with metal cations in nonaqueous media is first reported. Solubility data of 1 in various solvents were used to derive the standard Gibbs energies of solution, Delta G(s)degrees in these solvents. The effect of solvation in the different media was assessed from the Gibbs energy of transfer taking acetonitrile as a reference solvent. (1)H NMR studies of the interaction of 1 and metal cations were carried out in CD(3)CN and CD(3)OD and the data are reported. Conductance measurements revealed that this ligand forms lead(II) or zinc complexes of 1: 1 stoichiometry in acetonitrile. It also revealed a stoichiometry of two molecules of 1 per mercury(II) and two cadmiu (II) ions per molecule of 1. The addition of silver salt to 1 led to the precipitation of the silver-1 complex which was isolated and characterized by X-ray crystallography. At variance with conductance measurements in solution, in the solid state the X-ray structure show`s a 1:1 stoichiometry in the Hg(II) complex. The themiodynamics of complexation of 1 and these cations provide a quantitative assessment of the selective behavior of this ligand for ions of environmental relevance. |
Identificador |
JOURNAL OF PHYSICAL CHEMISTRY B, v.113, n.14, p.4775-4780, 2009 1520-6106 http://producao.usp.br/handle/BDPI/29951 10.1021/jp810170p |
Idioma(s) |
eng |
Publicador |
AMER CHEMICAL SOC |
Relação |
Journal of Physical Chemistry B |
Direitos |
restrictedAccess Copyright AMER CHEMICAL SOC |
Palavras-Chave | #ALKALI-METAL CATIONS #PANDEMIC INFLUENZA #CRYPTAND 222 #SOLID-STATE #COMPLEXATION #PARAMETERS #WATER #DERIVATIVES #SOLVENTS #SYSTEMS #Chemistry, Physical |
Tipo |
article original article publishedVersion |