Synthesis, x-ray structure and anion binding properties of a cryptand-like hybrid calixpyrrole
| Data(s) |
2010
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|---|---|
| Resumo |
The novel cryptand in/out-3, containing two tripyrrolemethane units briged by three 1,3- diisopropylidenbenzene arms was readily synthesized by a convergent three-step synthesis. It binds fluoride by inclusion with excellent selectivity with respect to a number of other tested anions. The structure of the free receptor and that of its fluoride complex were investigated in solution by NMR spectroscopy. The solid state X-ray structure of the free cryptand 3 was also determined. |
| Formato |
text text |
| Identificador |
http://centaur.reading.ac.uk/16568/2/FHK-JOC.pdf http://centaur.reading.ac.uk/16568/4/FHK-JOC-SI.pdf Cafeo, G., Colquhoun, H. M. <http://centaur.reading.ac.uk/view/creators/90000005.html>, Cuzzola, A., Gattuso, M., Kohnke, F. H., Valenti, L. and White, A. J. P. (2010) Synthesis, x-ray structure and anion binding properties of a cryptand-like hybrid calixpyrrole. Journal of Organic Chemistry, 75 (18). pp. 6263-6266. ISSN 1520-6904 doi: 10.1021/jo1010262 <http://dx.doi.org/10.1021/jo1010262> |
| Idioma(s) |
en en |
| Publicador |
American Chemical Society |
| Relação |
http://centaur.reading.ac.uk/16568/ creatorInternal Colquhoun, Howard M. 10.1021/jo1010262 |
| Tipo |
Article PeerReviewed |
