Frequency spectroscopy of irreversible electrochemical nucleation kinetics on the nanoscale
Data(s) |
2013
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Resumo |
An approach is developed for probing the thermodynamics and kinetics of irreversible electrochemical reactions on solid surfaces based on local frequency-voltage spectroscopy. For a model Li-ion conductor surface, two regimes for bias-controlled behavior are demonstrated and ascribed to the difference in the critical nucleus size. The electrostatic and electrochemical phenomena at the tip-surface junction are analyzed. These studies suggest an experimental pathway for exploring local electrochemical activity in solids. |
Identificador | |
Idioma(s) |
eng |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Kumar , A , Chen , C , Arruda , T M , Jesse , S , Ciucci , F & Kalinin , S V 2013 , ' Frequency spectroscopy of irreversible electrochemical nucleation kinetics on the nanoscale ' Nanoscale , vol 5 , no. 23 , pp. 11964-11970 . DOI: 10.1039/c3nr03953f |
Tipo |
article |