The structural characterization and hydroformylation activity of the tri-rhodium complex [Rh-3(mu(2)-dppm)(2)(mu(2)-CO)(3)(K-1-CO)(3)]BF4
| Data(s) |
01/10/2009
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| Resumo |
Rh-2(cod)(2)(mu(2)-dppm)(mu(2)-Cl)]BF4 (1) rearranges under carbon monoxide to give [Rh-3(mu(2)-dppm)(2)-(mu(2)-CO)(3)(K-1-CO)(3)]BF4 (2). Complex 2 has been structurally characterized by single crystal X-ray crystallography. The hydroformylation activities of 1 and 2 were compared for substrates styrene and 1-hexene and the activity of 2 found to be unexpectedly high. |
| Identificador |
http://dx.doi.org/10.1016/j.inoche.2009.08.024 http://www.scopus.com/inward/record.url?scp=70349433520&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Lorenzini , F , O'Hara , E , Qian , S , Marchetti , F , Birbeck , J M , Haynes , A , Blake , A J , Saunders , G & Marr , A 2009 , ' The structural characterization and hydroformylation activity of the tri-rhodium complex [Rh-3(mu(2)-dppm)(2)(mu(2)-CO)(3)(K-1-CO)(3)]BF4 ' Inorganic Chemistry Communications , vol 12 , no. 10 , pp. 1071-1073 . DOI: 10.1016/j.inoche.2009.08.024 |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600/1604 #Inorganic Chemistry #/dk/atira/pure/subjectarea/asjc/1600/1606 #Physical and Theoretical Chemistry #/dk/atira/pure/subjectarea/asjc/2500/2505 #Materials Chemistry |
| Tipo |
article |
