FT-jet spectroscopy: vibrational energy transfer in N2O


Autoria(s): Herman, Michel; Didriche, Keevin; Rizopoulos, Atina; Hurtmans, Daniel
Data(s)

2005

Resumo

A set-up combining a high resolution Fourier transform interferometer and a quadrupole mass spectrometer with a supersonic jet expansion produced thanks to a large turbomolecular pumping unit is described. A rotational temperature close to 3 K is demonstrated. Vibration-vibration energy transfer in the expansion affecting the v2 = 1 state in N2O is monitored in the presence of various collision partners. The transfer from the v 2 = 1 state of N2O towards the quasi resonant, lower energy v2 = 1 state of OCS is demonstrated, in particular. © 2005 Elsevier B.V. All rights reserved.

info:eu-repo/semantics/published

Formato

1 full-text file(s): application/pdf

Identificador

uri/info:doi/10.1016/j.cplett.2005.08.087

https://dipot.ulb.ac.be/dspace/bitstream/2013/76261/1/Didriche_1.pdf

http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/76261

Idioma(s)

en

Direitos

1 full-text file(s): info:eu-repo/semantics/restrictedAccess

Fonte

Chemical physics letters, 414 (4-6

Palavras-Chave #Chimie #Physique atomique et nucléaire #Spectroscopie [électromagnétisme, optique, acoustique]
Tipo

info:eu-repo/semantics/article

info:ulb-repo/semantics/articlePeerReview

info:ulb-repo/semantics/openurl/article