Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water
| Data(s) |
01/06/2005
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| Resumo |
Pd-supported on WO3-ZrO2 (W/Zr atomic ratio=0.2) calcined at 1073 K was found to be highly active and selective for gas-phase oxidation of ethylene to acetic acid in the presence of water at 423 K and 0.6 MPa. Contact time dependence demonstrated that acetic acid is formed via acetaldehyde formed by a Wacker-type reaction, not through ethanol by hydration of ethylene. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
楚文玲; Yasunobu Ooka; Yuichi Kamiya and Toshio Okuhara.Reaction path for oxidation of ethylene to acetic acid over Pd/WO3-ZrO2 in the presence of water,Catalysis Letters,2005,101(34):225-228 |
| Palavras-Chave | #ethylene oxidation #acetic acid #acetaldehyde #reaction path #Pd/WO3-ZrO2 #Wacker-type reaction |
| Tipo |
期刊论文 |
