Activation of a ring methyl substituent in pentamethylcyclopentadienyl rhenium(V) compounds: Synthesis and characterization of the 1,2,3,4-tetramethyl-5,6-dihydrofulvene-5,6-dithiolato complex [ReO{(S)(SCH2)C(5)Me(4)}(C(5)Me(5))]
| Data(s) |
1996
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|---|---|
| Resumo |
Reaction of the half-sandwich rhenium(v) complexes [Re-Cl-4(C(5)Me(5))] or [Re(O)Cl-2(C(5)Me(5))] with H2S in chloroform in the presence of pyridine leads to the chiral dithiolato complex [ReO((S)(SCH2)C(5)Me(4))(C(5)Me(5))] 1. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Herberhold M;Jin GX;Rheingold AL.Activation of a ring methyl substituent in pentamethylcyclopentadienyl rhenium(V) compounds: Synthesis and characterization of the 1,2,3,4-tetramethyl-5,6-dihydrofulvene-5,6-dithiolato complex [ReO{(S)(SCH2)C(5)Me(4)}(C(5)Me(5))],CHEMICAL COMMUNICATIONS,1996,(23):2645-2646 |
| Palavras-Chave | #MAIN-GROUP ELEMENTS #TRANSITION-METALS #MULTIPLE BONDS #MOLECULAR-STRUCTURE #SULFUR #LIGANDS #CRYSTAL #OXIDES #OXYGEN #<(MU-ETA-3-C5ME5O3)V(O)>2 |
| Tipo |
期刊论文 |
