Physical diffusion and electron-transfer dynamics of electroactive solutes in polymer electrolytes .1. Effect of the nature of electroactive solutes
Data(s) |
1997
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Resumo |
The diffusion coefficients(D-app) and the heterogeneous electron-transfer rate constants(k(s)) for ferrocene and its seven derivatives in MPEG/LiClO4 electrolyte were determined by using steady-state voltammetry. The two parameters increase with increasing temperature, indicating Arrhenius behavior. The effects of the nature of electroactive solute molecules on D-app, k(s), and the half-wave potentials(E-1/2) are discussed. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
Ding LM;Zhou HF;Shi Z;Dong SJ.Physical diffusion and electron-transfer dynamics of electroactive solutes in polymer electrolytes .1. Effect of the nature of electroactive solutes,CHINESE CHEMICAL LETTERS,1997,8(9):825-828 |
Palavras-Chave | #VOLTAMMETRY #FILMS |
Tipo |
期刊论文 |