Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium


Autoria(s): Li HM; Ye XK; Yang XG; Wu Y
Data(s)

1997

Resumo

The catalytic oxidation of cyclohexene to cyclohexanone using Pd(OAc)(2)/HQ/FePc was investigated in an acidic aqueous solution of acetonitrile. The role of each component of this system in the oxidation of cyclohexene was explored by means of UV-VIS, IR, XPS spectroscopy and. cyclic voltammetry, respectively. Based on the experimental results, the mechanism of the oxidation of cyclohexene catalyzed by Pd(OAc)(2)/HQ/FePc was elucidated.

Identificador

http://202.98.16.49/handle/322003/23841

http://www.irgrid.ac.cn/handle/1471x/156648

Idioma(s)

英语

Fonte

Li HM;Ye XK;Yang XG;Wu Y.Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium,CHINESE JOURNAL OF CHEMISTRY,1997,15(6):512-527

Palavras-Chave #MULTISTEP ELECTRON-TRANSFER #ELECTROCHEMICAL PROPERTIES #MOLECULAR-OXYGEN #OLEFINS #KETONES #IRON
Tipo

期刊论文